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Synthesis, crystal structures and catalytic properties of three-dimensional nickel(II) and manganese(II) coordination polymers with dicarboxylate and semi-rigid bis(imidazole) ligands

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Abstract

Two coordination polymers (CPs), namely [Ni(L)(chdc)] n (1) and [Mn(L)(ndc)(H2O)] n (2) (L = 4,4′-bis(imidazol-1-ylmethyl)biphenyl, H2chdc = 1,2-cyclohexanedicarboxylic acid, H2ndc = 2,6-naphthalenedicarboxylic acid), have been hydrothermally synthesized and characterized by physicochemical and spectroscopic methods and also by single-crystal diffraction. Both CPs feature 3D-diamond-like networks with point symbol of 66; CP-1 displays a 2-fold interpenetrated net, while CP-2 presents a non-interpenetrated framework. The thermal stabilities, solid-state luminescence properties and catalytic activities of both CPs for degradation of methyl orange in a Fenton-like process were investigated.

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Acknowledgments

The work was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation–Steel and Iron Foundation of Hebei Province (B2015209299).

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Authors and Affiliations

  1. Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, College of Chemical Engineering, North China University of Science and Technology, 063009, Tangshan, Hebei, People’s Republic of China

    Hai-Ning Chang, Yong-Guang Liu, Zeng-Chuan Hao, Guang-Hua Cui & Sheng-Chun Wang

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  1. Hai-Ning Chang
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  2. Yong-Guang Liu
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  3. Zeng-Chuan Hao
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  4. Guang-Hua Cui
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  5. Sheng-Chun Wang
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Correspondence to Guang-Hua Cui or Sheng-Chun Wang.

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Chang, HN., Liu, YG., Hao, ZC. et al. Synthesis, crystal structures and catalytic properties of three-dimensional nickel(II) and manganese(II) coordination polymers with dicarboxylate and semi-rigid bis(imidazole) ligands. Transit Met Chem 41, 693–699 (2016). https://doi.org/10.1007/s11243-016-0070-3

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  • DOI: https://doi.org/10.1007/s11243-016-0070-3

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