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Synthetic and structural studies of tolyl-dithiolate diiron carbonyl complexes with tris(aryl)phosphine co-ligands

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Abstract

Reaction of [μ-SC6H3(CH3)S-μ]Fe2(CO)6 (1) with 2 equivalents of PPh3 gave the monosubstituted complex [μ-SC6H3(CH3)S-μ]Fe2(CO)5(PPh3) (2) plus the disubstituted [μ-SC6H3(CH3)S-μ]Fe2(CO)4(PPh3)2 (3), while the complexes [μ-SC6H3(CH3)S-μ]Fe2(CO)5[P(3-C6H4CH3)3] (4) and [μ-SC6H3(CH3)S-μ]Fe2(CO)5[P(4-C6H4F)3] (5) were prepared by the reactions of 1 with P(3-C6H4CH3)3 or P(4-C6H4F)3 in the presence of Me3NO. Complexes 3–5 were characterized by IR, NMR spectroscopy and single-crystal X-ray diffraction analysis. The molecular structures of 3–5 reveal that in each case, the phosphine ligand occupies the apical position in an overall distorted square pyramidal iron(I) complex geometry.

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Acknowledgments

The author gratefully acknowledges the support of the Zhejiang Provincial Natural Science Foundation (No. LY16B020009) and K.C.Wong Education Foundation.

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  1. College of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, 315016, China

    Xu-Feng Liu

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  1. Xu-Feng Liu
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Correspondence to Xu-Feng Liu.

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Liu, XF. Synthetic and structural studies of tolyl-dithiolate diiron carbonyl complexes with tris(aryl)phosphine co-ligands. Transit Met Chem 41, 547–554 (2016). https://doi.org/10.1007/s11243-016-0051-6

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