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Synthesis, spectroscopy and crystal structures of three diiron ethanedithiolate complexes with tertiary phosphine ligands: vinyldiphenylphosphine, 4-(dimethylamino)phenylphosphine or bis(4-methoxyphenyl)phenylphosphine

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Abstract

Three diiron ethanedithiolate complexes of tertiary phosphine ligands, namely (µ-SCH2CH2S-μ)Fe2(CO)5L [L = Ph2PCH=CH2, 2; Ph2P(C6H4NMe2-4), 3; PhP(C6H4OMe-4)2, 4], were synthesized by carbonyl substitution of the parent complex (µ-SCH2CH2S-μ)Fe2(CO)6 (1) with the corresponding monophosphine ligands in the presence of Me3NO·2H2O as a decarbonylating agent. Complexes 2‒4 were characterized by elemental analysis and spectroscopy; in addition, their molecular structures were determined by X-ray crystallography.

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Acknowledgements

The authors gratefully acknowledge the support of the Natural Science Foundation of Zhejiang Province (No. LY16B020009).

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Authors and Affiliations

  1. School of Pharmacy, Henan University of Chinese Medicine, Zhengzhou, 450046, China

    Wei Gao

  2. Zhengzhou Second Hospital, Zhengzhou, 450046, China

    Xue-Quan Guo

  3. School of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo, 315211, China

    Xu-Feng Liu

Authors
  1. Wei Gao
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  2. Xue-Quan Guo
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Corresponding author

Correspondence to Xu-Feng Liu.

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Gao, W., Guo, XQ. & Liu, XF. Synthesis, spectroscopy and crystal structures of three diiron ethanedithiolate complexes with tertiary phosphine ligands: vinyldiphenylphosphine, 4-(dimethylamino)phenylphosphine or bis(4-methoxyphenyl)phenylphosphine. Transit Met Chem 44, 5–10 (2019). https://doi.org/10.1007/s11243-018-0263-z

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