Skip to main content
SpringerLink
Log in

Manganese(II), nickel(II), and cadmium(II) coordination polymers with tetrafluoroterephthalate: syntheses, crystal structures, and luminescence properties

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Three new coordination polymers, [Mn(BDC-F4)(DMF)2(H2O)2] n (1), [Ni(BDC-F4)(DMF)(EtOH)] n (2), and [Cd(BDC-F4)(DMF)(EtOH)] n (3), have been synthesized by assembling transition metal salts with the rigid ligand tetrafluoroterephthalic acid (H2BDC-F4) in mixed EtOH/DMF solvent at pH ca. 2. For complex 1, the octahedral coordination geometry of the MnII center is provided by two oxygen atoms from two dianionic BDC-F4 ligands, two DMF ligands and two aqua ligands, giving a 1-D linear chain array. For complex 2, the NiII center is coordinated by two dianionic BDC-F4 ligands, two EtOH ligands and two DMF ligands, resulting in a 1-D chain structure. For complex 3, the CdII center is coordinated by four dianionic BDC-F4 ligands, one EtOH ligand and one DMF ligand, generating a 2-D layered structure. The results suggest that both the metal and the solution pH play an important role in the formation of the complexes. The spectroscopic, thermal, and luminescence properties of the complexes have been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Scheme 2
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Suh MP, Park HJ, Prasad TK, Lim DW (2012) Chem Rev 112:782–835

    Article  CAS  Google Scholar 

  2. Cui Y, Yue Y, Qian G, Chen B (2012) Chem Rev 112:1126–1162

    Article  CAS  Google Scholar 

  3. Zhang W, Xiong R-G (2012) Chem Rev 112:1163–1195

    Article  CAS  Google Scholar 

  4. Yoon M, Srirambalaji R, Kim K (2012) Chem Rev 112:1196–1231

    Article  CAS  Google Scholar 

  5. Perry JJ IV, Perman JA, Zaworotko MJ (2009) Chem Soc Rev 38:1400–1417

    Article  CAS  Google Scholar 

  6. Moulton B, Zaworotko MJ (2001) Chem Rev 101:1629–1658

    Article  CAS  Google Scholar 

  7. Elsaidi SK, Mohamed MH, Wojtas L, Chanthapally A, Pham T, Space B, Vittal JJ, Zaworotko MJ (2014) J Am Chem Soc 136:5072–5077

    Article  CAS  Google Scholar 

  8. Phan A, Doonan CJ, Uribe-Romo FJ, Knobler CB, O’Keeffe M, Yaghi OM (2010) Acc Chem Rev 43:58–67

    Article  CAS  Google Scholar 

  9. Li M, Li D, O’Keeffe M, Yaghi OM (2014) Chem Rev 114:1343–1370

    Article  CAS  Google Scholar 

  10. Long JR, Yaghi OM (2009) Chem Soc Rev 38:1213–1214

    Article  CAS  Google Scholar 

  11. O’Keeffe M, Yaghi OM (2012) Chem Rev 112:675–702

    Article  Google Scholar 

  12. Hu T-P, He H-Y, Dai F-G, Zhao X-L, Sun D-F (2010) CrystEngComm 12:2018–2020

    Article  CAS  Google Scholar 

  13. Zhou X-P, Xu Z, Zeller M, Hunter AD, Chui SS-Y, Che C-M (2008) Inorg Chem 47:7459–7461

    Article  CAS  Google Scholar 

  14. Shi L-X, Wu C-D (2011) Inorg Chem Commun 14:569–572

    Article  CAS  Google Scholar 

  15. Dietzel PDC, Johnsen RE, Fjellvág H, Bordiga S, Groppo E, Chavan S, Blom R (2008) Chem Commum 41:5125–5127

    Article  Google Scholar 

  16. He J, Yang Z-T, Zeller M, Hunter AD, Lin J-H (2009) J Solid State Chem 182:1821–1826

    Article  CAS  Google Scholar 

  17. Chen S-C, Zhang Z-H, Huang K-L, Chen Q, He M-Y, Cui A-J, Li C, Liu Q, Du M (2008) Cryst Growth Des 8:3437–3445

    Article  CAS  Google Scholar 

  18. Chen T-H, Popov I, Zenasni O, Daugulis O, Miljanić OŠ (2013) Chem Commun 49:6846–6848

    Article  CAS  Google Scholar 

  19. Meek ST, Perry JJ IV, Teich-McGoldrick SL, Greathouse JA, Allendorf MD (2011) Cryst Growth Des 11:4309–4312

    Article  CAS  Google Scholar 

  20. Wang Z, Kravtsov VC, Walsh RB, Zaworotko MJ (2007) Cryst Growth Des 6:1154–1162

    Article  Google Scholar 

  21. Chen B, Yang Y, Zapata F, Qian G, Luo Y, Zhang J, Lobkovsky EB (2006) Inorg Chem 45:8882–8886

    Article  CAS  Google Scholar 

  22. Kitaura R, Iwahori F, Matsuda R, Kitagawa S, Kubota Y, Takata M, Kobayashi TC (2004) Inorg Chem 43:6522–6524

    Article  CAS  Google Scholar 

  23. Seidel C, Ahlers R, Ruschewitz U (2011) Cryst Growth Des 11:5053–5063

    Article  CAS  Google Scholar 

  24. Seidel C, Lorbeer C, Cybińska J, Mudring A-V, Ruschewitz U (2012) Inorg Chem 51:4679–4688

    Article  CAS  Google Scholar 

  25. Chen S-C, Zhang Z-H, Chen Q, Wang L-Q, Xu J, He M-Y, Du M, Yang X-P, Jones RA (2013) Chem Commun 49:1270–1272

    Article  CAS  Google Scholar 

  26. Chen S-C, Zhang Z-H, Kuang K-L, Luo H-K, He M-Y, Du M, Chen Q (2013) CrystEngComm 15:9613–9622

    Article  CAS  Google Scholar 

  27. Chen S-C, Zhang Z-H, Chen Q, Gao H-B, Liu Q, He M-Y, Du M (2009) Inorg Chem Commun 12:835–838

    Article  CAS  Google Scholar 

  28. Blessing RH (1995) Acta Cryst A 51:33–38

    Article  Google Scholar 

  29. Sheldrick GM (1997) SHELXS-97 and SHELXL-97. University of Göttingen, Germany

    Google Scholar 

  30. Zhu E-J, Liu Q, Yu L-L, He M-Y, Chen Q, Chen Z-D, Chen S-C, Zhang Z-H (2011) Syn React Inorg Met-Org Nano-Met Chem 41:1299–1304

    Article  CAS  Google Scholar 

  31. Yersin H, Vogler A (1987) Photochemistry and photophysics of coordination compounds. Springer, Berlin

    Book  Google Scholar 

  32. Zheng S-L, Yang J-H, Yu X-L, Chen X-M, Wong W-T (2004) Inorg Chem 43:830–838

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We gratefully acknowledge financial support by the National Natural Science Foundation of China (21201026), the Nature Science Foundation of Jiangsu Province (BK20131142), and A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Author information

Authors and Affiliations

  1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, People’s Republic of China

    Feng Tian, Hong-Dan Wang, Ming-Yang He, Jing Zhong, Qun Chen & Sheng-Chun Chen

  2. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, People’s Republic of China

    Qun Chen & Sheng-Chun Chen

Authors
  1. Feng Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hong-Dan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ming-Yang He
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jing Zhong
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Qun Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Sheng-Chun Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Ming-Yang He or Sheng-Chun Chen.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tian, F., Wang, HD., He, MY. et al. Manganese(II), nickel(II), and cadmium(II) coordination polymers with tetrafluoroterephthalate: syntheses, crystal structures, and luminescence properties. Transition Met Chem 39, 867–874 (2014). https://doi.org/10.1007/s11243-014-9870-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-014-9870-5

Keywords

Search

Navigation