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Synthesis, characterization and molecular structure of titanium alkoxide complexes with aromatic oxime ligands

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Abstract

Stoichiometric reactions of pyridine-2-aldoxime (HL1) with titanium 2-propoxide and of salicylaldoxime (H2L2) with titanium 2-propoxide or titanium ethoxide in toluene at room temperature resulted in the formation of [Ti2(μ-O)(μ-L)2(OR)4] (for L1, R = iPr; for L2, R = iPr or Et). These complexes were all characterized by spectroscopic methods; in addition, the molecular structure of [Ti2(μ-O)(μ-L1)2(OiPr)4] was determined by single-crystal X-ray diffraction. The titanium atoms have distorted octahedral geometries that share an apex through a bridging oxygen. Each monoanionic L1 is chelated to one titanium atom through its pyridine and oximate nitrogen atoms and to a second titanium atom through its oximate oxygen atom.

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References

  1. Bradley DC, Mehrotra RC, Rothwell IP, Singh A (2001) Alkoxo and aryloxo derivatives of metals. Academic Press, London

    Google Scholar 

  2. Mirzaee M, Tamizkar T, Mohammadnezhad G, Khavasi HR, Amini MM (2011) C R Chimie 14:927

    Article  CAS  Google Scholar 

  3. Corden JP, Errington W, Moore P, Partridge MG, Wallbridge MGH (2004) Dalton Trans: 1846

  4. Ugrinova V, Ellis GA, Brown SN (2004) Chem Commun: 468

  5. Thorpe JM, Beddoes RL, Collison D, Garner CD, Helliwell M, Holmes JM, Tasker PA (1999) Angew Chem Int Ed 38:1119

    Article  CAS  Google Scholar 

  6. Mukherjee S, Patel BA, Bhaduri S (2009) Organomet 28:3074

    Article  CAS  Google Scholar 

  7. Raptopoulou CP, Psycharis V (2008) Inorg Chem Commun 11:1194

    Article  CAS  Google Scholar 

  8. Konidaris KF, Raptopoulou CP, Psycharis V, Perlepes SP, Manessi-Zoupa E, Stamatatos TC (2010) Bioinorg Chem Appl. doi:10.1155/2010/159656

  9. Birnara C, Kessler VG, Papaefstathiou GS (2009) Polyhedron 28:3291

    Article  CAS  Google Scholar 

  10. Amini MM, Mirzaee M, Ng SW (2004) Acta Cryst E60:m53

    Google Scholar 

  11. Milios CJ, Stamatatos TC, Perlepes SP (2006) Polyhedron 25:134

    Article  CAS  Google Scholar 

  12. Chaudhuri P, Weyhermuller T, Wagner R, Khanra S, Biswas B, Bothe E, Bill E (2007) Inorg Chem 46:9003

    Article  CAS  Google Scholar 

  13. Alexandropoulos DI, Papatriantafyllopoulou C, Aromi G, Roubeau O, Teat SJ, Perlepes SP, Christou G, Stamatatos TC (2010) Inorg Chem 49:3962

    Article  CAS  Google Scholar 

  14. Khanra S, Biswas B, Golze C, Buchner B, Kataev V, Weyhermuller T, Chaudhuri P (2007) Dalton Trans: 481

  15. Stamatatos TC, Katsoulakou E, Terzis A, Raptopoulou CP, Winpenny REP, Perlepes SP (2009) Polyhedron 28:1638

    Article  CAS  Google Scholar 

  16. Miyasaka H, Julve M, Yamashita M, Clerac R (2009) Inorg Chem 48:3420

    Article  CAS  Google Scholar 

  17. Torabi AA, Kian R, Soudozi A, Welter R (2005) Z Kristallogr NCS 220:613

    CAS  Google Scholar 

  18. Torabi AA, Soudozi A, Welter R (2007) Z Kristallogr NCS 222:197

    CAS  Google Scholar 

  19. Nordquest KW, Phelps DW, Little WF, Hodgson DJ (1976) J Am Chem Soc 98:1104

    Article  CAS  Google Scholar 

  20. Papatriantafyllopoulou C, Stamatatos TC, Efthymiou CG, Cunha-Silva L, Almeida Paz FA, Perlepes SP, Christou G (2010) Inorg Chem 49:9743

    Article  CAS  Google Scholar 

  21. Davidson MG, Johnson AL, Jones MD, Lunn MD, Mahon MF (2007) Polyhedron 26:975

    Article  CAS  Google Scholar 

  22. Tan X, Han X, Feng J, Liu J, Zhou Y (2012) Inorg Chem Commun 15:5

    Article  CAS  Google Scholar 

  23. Cabeza JA, Rio I, Riera V, Suarez M, Alvarez-Rua C, Garcia-Granda S, Chuang SH, Hwu JR (2003) Eur J Inorg Chem: 4159

  24. Liu S, Zhu H, Zubieta J (1989) Polyhedron 8:2473

    Article  CAS  Google Scholar 

  25. Zerbib V, Robert F, Gouzerh F (1994) Chem Commun: 2179

  26. Amini MM, Mirzaee M, Ng SW (2004) Acta Cryst E60:m145

    Google Scholar 

  27. Mirzaee M, Amini MM (2005) Appl Organometal Chem 19:339

    Article  CAS  Google Scholar 

  28. Kessler VG, Spijksma GI, Seisenbaeva GA, Hakansson S, Blank DHA, Bouwmeester HJM (2006) J Sol-Gel Sci Technol 40:163

    Article  CAS  Google Scholar 

  29. Amini MM, Mahmoodi A, Mirzaee M, Ng SW (2004) Acta Cryst E60:m1053

    Google Scholar 

  30. Amini MM, Mirzaee M, Yeganeh F, Khavasi HR, Mirzaei P, Ng SW (2008) Transition Met Chem 33:79

    Article  CAS  Google Scholar 

  31. Aakeroy CB, Beatty AM, Leinen DS (2000) Cryst Eng Comm 2:145

    Article  Google Scholar 

  32. Furniss BS, Hannaford AJ, Rogers V, Smith PWG, Tatchell AR (1986) Vogels textbook of practical organic chemistry. Longman, New York

    Google Scholar 

  33. Stoe and Cie (2005) X-AREA (Version 1.30), GmbH: Darmstadt, Germany

  34. Stoe and Cie (2005) X-RED (Version 1.28b), GmbH: Darmstadt, Germany

  35. Stoe and Cie (2004) X-SHAPE (Version 2.05), GmbH: Darmstadt, Germany

  36. Sheldrick GM (1997) SHELX97. University of Göttingen, Germany

    Google Scholar 

  37. Stoe and Cie (2000) X-STEP32 (Version 1.07b), GmbH: Darmstadt, Germany

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Acknowledgments

The authors thank the Vice-President’s Office for Research Affairs of Shahrood University of Technology and Shahid Beheshti University for supporting this work.

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Authors and Affiliations

  1. Department of Chemistry, Shahrood University of Technology, Shahrood, Iran

    Mahdi Mirzaee, Mahmood Norouzi & Masoomeh Faghani

  2. Department of Chemistry, Shahid Beheshti University, G. C., 1983963113, Tehran, Iran

    Mostafa M. Amini & Hamid Reza Khavasi

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  1. Mahdi Mirzaee
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  2. Mahmood Norouzi
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  3. Masoomeh Faghani
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  4. Mostafa M. Amini
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  5. Hamid Reza Khavasi
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Correspondence to Mahdi Mirzaee.

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Mirzaee, M., Norouzi, M., Faghani, M. et al. Synthesis, characterization and molecular structure of titanium alkoxide complexes with aromatic oxime ligands. Transition Met Chem 39, 55–62 (2014). https://doi.org/10.1007/s11243-013-9773-x

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  • DOI: https://doi.org/10.1007/s11243-013-9773-x

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