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Synthesis, crystal structures and catalytic properties of Ag(I) and Co(II) 1D coordination polymers constructed from bis(benzimidazolyl)butane

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Abstract

Two metal–organic coordination polymers, {Co(bbbi)0.5(bm)(Hbtc)} n (1) and {Ag2(bbbi)2(ntp)(H2O)·4H2O} n (2), [bbbi = 1,1-(1,4-butanediyl)bis-1H-benzimidazole, bm = benzimidazole, H3btc = 1,2,4-trimellitic acid, and H2ntp = 2-nitroterephthalic acid], have been hydrothermally synthesized and characterized by physico-chemical and spectroscopic methods and single-crystal diffraction. 1 Features a 1D ladder-like chain and is further connected by O–H···O hydrogen bonding interactions to yield a 3D supramolecular architecture. 2 Possesses a 1D infinite zigzag chain connected by bbbi ligands in bis-monodentate mode, which is further extended into a 3D complicated supramolecular network by face-to-face π–π stacking interactions and O–H···O hydrogen bonds. Moreover, both compounds exhibit catalytic properties on degradation of methyl orange in Fenton-like process.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, 063009, Hebei, People’s Republic of China

    Li Qin, Shu Lin Xiao, Pei Juan Ma & Guang Hua Cui

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  1. Li Qin
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  2. Shu Lin Xiao
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  3. Pei Juan Ma
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  4. Guang Hua Cui
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Correspondence to Guang Hua Cui.

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Qin, L., Xiao, S.L., Ma, P.J. et al. Synthesis, crystal structures and catalytic properties of Ag(I) and Co(II) 1D coordination polymers constructed from bis(benzimidazolyl)butane. Transition Met Chem 38, 627–633 (2013). https://doi.org/10.1007/s11243-013-9730-8

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  • DOI: https://doi.org/10.1007/s11243-013-9730-8

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