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A heterogenized vanadium oxo-aroylhydrazone catalyst for efficient and selective oxidation of hydrocarbons with hydrogen peroxide

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Abstract

A hydrazone Schiff base ligand derived from salicylaldehyde and benzhydrazide has been synthesized and reacted with vanadium(IV) leading to the corresponding vanadium(V) complex. The complex has been anchored on the surface of functionalized silica gel by N,O-coordination to the covalently Si–O bound modified salicylaldiminato ligand. The supported complex has been evaluated as a catalyst for hydrocarbon oxidation with hydrogen peroxide in acetonitrile. The heterogeneous system proved to be an efficient catalyst and was able to activate hydrogen peroxide toward the oxidation of alkenes, alkanes, benzene, and alkylaromatic compounds with more than 2,500 h−1 activity.

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Acknowledgments

Authors are thankful to the University of Zanjan for financial support of this study.

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Authors and Affiliations

  1. Department of Chemistry, University of Zanjan, 45195-313, Zanjan, Islamic Republic of Iran

    Hassan Hosseini Monfared, Vahideh Abbasi, Adineh Rezaei & Massomeh Ghorbanloo

  2. Materials and Energy Research Center, 14155-4777, Tehran, Islamic Republic of Iran

    Alireza Aghaei

Authors
  1. Hassan Hosseini Monfared
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  2. Vahideh Abbasi
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  3. Adineh Rezaei
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  4. Massomeh Ghorbanloo
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  5. Alireza Aghaei
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Correspondence to Hassan Hosseini Monfared.

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Hosseini Monfared, H., Abbasi, V., Rezaei, A. et al. A heterogenized vanadium oxo-aroylhydrazone catalyst for efficient and selective oxidation of hydrocarbons with hydrogen peroxide. Transition Met Chem 37, 85–92 (2012). https://doi.org/10.1007/s11243-011-9561-4

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  • DOI: https://doi.org/10.1007/s11243-011-9561-4

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