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Biomimetic epoxidation of alkenes with sodium periodate catalyzed by tetraphenylporphyrinatomanganese(III) chloride supported on multiwall carbon nanotubes

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Abstract

The biomimetic epoxidation of alkenes catalyzed by tetraphenylporphyrinatomanganese(III) chloride, [Mn(TPP)Cl], immobilized on multiwall carbon nanotubes modified with 4-aminopyridine and 4-aminophenol is reported. These heterogenized catalysts were used as efficient and reusable catalysts for epoxidation of a variety of cyclic and linear alkenes with sodium periodate under mild conditions. The catalysts, [Mn(TPP)Cl@amine-MWCNT], were characterized by physico-chemical and spectroscopic methods. The effect of ultrasonic irradiation on these catalytic systems was also investigated. The catalysts were reused several times without loss of their activity.

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Acknowledgments

We acknowledge the support of this work by Center of Excellence of Chemistry of University of Isfahan (CECUI).

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Authors and Affiliations

  1. Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan, 81746-73441, Iran

    Maryam Zakeri, Majid Moghadam, Iraj Mohammadpoor-Baltork, Shahram Tangestaninejad, Valiollah Mirkhani, Ahmad Reza Khosropour & Mohammad Alizadeh

Authors
  1. Maryam Zakeri
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  2. Majid Moghadam
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  3. Iraj Mohammadpoor-Baltork
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  4. Shahram Tangestaninejad
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  5. Valiollah Mirkhani
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  6. Ahmad Reza Khosropour
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  7. Mohammad Alizadeh
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Correspondence to Majid Moghadam.

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Zakeri, M., Moghadam, M., Mohammadpoor-Baltork, I. et al. Biomimetic epoxidation of alkenes with sodium periodate catalyzed by tetraphenylporphyrinatomanganese(III) chloride supported on multiwall carbon nanotubes. Transition Met Chem 37, 45–53 (2012). https://doi.org/10.1007/s11243-011-9555-2

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  • DOI: https://doi.org/10.1007/s11243-011-9555-2

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