Skip to main content
SpringerLink
Log in

Synthesis and characterization of two inorganic–organic hybrid polyoxometalates bridged by Keggin-type building blocks and copper(II) organonitrogen complexes

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Two new inorganic–organic hybrid compounds, namely [Cu(dab)2]2[α-SiW12O40]·H2O (dab = 1,2-diaminobenzene) and [Cu(dafo)3]2[Cu(dafo)2(H2O)2][α-PMo12O40]2·4H2O (dafo = 4,5-diaza- fluorene-9-one) have been synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction. [Cu(dab)2]2[α-SiW12O40]·H2O exhibits an alternating 2D ladder-like structure built of [α-SiW12O40]4− and [Cu(L)2]2+ units. As the inorganic building block, the Keggin-type polyoxoanion [α-SiW12O40]4− is linked to two metal–organic complexes [Cu(dab)2]2+ through different kinds of oxygen atoms (terminal and bridging). [Cu(dafo)3]2[Cu(dafo)2(H2O)2][α-PMo12O40]2·4H2O shows an extended 3D supramolecular network via hydrogen bonding. Both complexes were characterized by physico-chemical and spectroscopic methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Müller A, Reuter H, Dillinger S (1995) Angew Chem Int Ed 34:2311

    Article  Google Scholar 

  2. Pope MT, Müller A (1991) Angew Chem Int Ed 30:34

    Article  Google Scholar 

  3. Hagrman D, Haushalter RC, Zubieta J (1998) Chem Mater 10:361

    Article  CAS  Google Scholar 

  4. Yaghi QM (1998) Nature 120:8571

    Google Scholar 

  5. Xu Y, Zhu HG, Cai H, You XZ (1999) Chem Commun 787

  6. Chen Q, Hill CL (1996) Inorg Chem 35:2403

    Article  CAS  Google Scholar 

  7. Dai LM, You WS, Wang EB, Wu SX, Su ZM, Du QH, Zhao Y, Fang Y (2009) Cryst Grow Des 9:2110

    Article  CAS  Google Scholar 

  8. Li YG, Dai LM, Wang YH, Wang XL, Wang EB, Su ZM, Xu L (2007) Chem Commun 2593

  9. Dai LM, You WS, Li YG, Wang EB, Huang CY (2009) Chem Commun 2721

  10. An HY, Wang EB, Xiao DR, Li YG, Su ZM, Xu L (2006) Angew Chem Int Ed 45:904

    Article  CAS  Google Scholar 

  11. Jin H, Wang XL, Qi YF, Wang EB (2007) Inorg Chim Acta 360:3347

    Article  CAS  Google Scholar 

  12. Meng JX, Wang XL, Ma Y, Wang EB, Xu XX (2008) J Coord Chem 61:2853

    Article  CAS  Google Scholar 

  13. Uchida S, Kawamoto R, Tagami H, Nakagawa Y, Mizuno N (2008) J Am Chem Soc 130:12370

    Article  CAS  Google Scholar 

  14. Tagami H, Uchida S, Mizuno N (2009) Angew Chem Int Ed 48:6160

    Article  CAS  Google Scholar 

  15. Uehara K, Kasai K, Mizuno N (2007) Inorg Chem 46:2563

    Article  CAS  Google Scholar 

  16. Jiang CJ, Lesbani A, Kawamoto R, Uchida S, Mizuno N (2006) J Am Chem Soc 128:14240

    Article  CAS  Google Scholar 

  17. Uchida S, Kawamoto R, Mizuno N (2006) Inorg Chem 45:5136

    Article  CAS  Google Scholar 

  18. Wang XL, Qin C, Wang EB, Su ZM (2007) Chem Commun 4245

  19. Yu F, Kong XJ, Zheng YY, Ren YP, Long LS, Huang RB, Zheng LS (2009) J Chem Soc Dalton Trans 9503

  20. Ren YP, Kong XJ, Long LS, Huang RB, Zheng LS (2006) Cryst Growth Des 6:572

    Article  CAS  Google Scholar 

  21. Ren YP, Kong XJ, Hu XY, Sun M, Long LS (2006) Inorg Chem 45:4016

    Article  CAS  Google Scholar 

  22. Chen JX, Lan TY, Huang YB, Wei CX, Li ZS (2006) J Solid State Chem 179:1904

    Article  CAS  Google Scholar 

  23. Meng JX, Wang XL, Ma Y, Wang EB, Xu XX (2008) J CoordChem 61:2853

    CAS  Google Scholar 

  24. Smith PM (1972) Diss Abstr B32:5136

    Google Scholar 

  25. Te′ze′ A, Herve′ G (1990) Inorganic synthesis, vol 27. Wiley, New York, p 85

    Google Scholar 

  26. Sheldrick GM (1997) SHELXS-97, program for crystal structure solution. University of Göttingen, Germany

    Google Scholar 

  27. Claud RD, Michael F, Raymonde F (1983) Inorg Chem 22:207

    Article  Google Scholar 

Download references

Acknowledgments

We thank the Training Fund of NENU’s Scientific Innovation Project (NENU-STC08008) and the Analysis and Testing Foundation of Northeast Normal University.

Author information

Authors and Affiliations

  1. Institute of Functional Polyoxometalate Chemistry, Faculty of Chemistry, Northeast Normal University, Renmin Road No. 5268, 130024, Changchun, Jilin, People’s Republic of China

    Fang-Fang Dong, Liang Che, Luo-Lan Li & Fang Luo

Authors
  1. Fang-Fang Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Liang Che
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Luo-Lan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Fang Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Fang Luo.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 1362 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dong, FF., Che, L., Li, LL. et al. Synthesis and characterization of two inorganic–organic hybrid polyoxometalates bridged by Keggin-type building blocks and copper(II) organonitrogen complexes. Transition Met Chem 36, 125–130 (2011). https://doi.org/10.1007/s11243-010-9444-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-010-9444-0

Keywords

Search

Navigation