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Iron(III) complex of a tridentate NNN type ligand: synthesis, X-ray structure, thermal analysis and voltammetric studies

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Abstract

A mononuclear iron(III) complex with 2,6-bis(3,4,5-trimethyl-N-pyrazolyl)pyridine (btmpp) has been synthesized, and characterized by X-ray crystallography, IR, UV–Vis and TGA–DTA methods. The Fe(III/II) couple was characterized by way of cyclic voltammetry using DMF solvent, where the complex was observed to have an irreversible behaviour.

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Acknowledgement

The financial support of the Scientific and Technical Research Council of Turkey (TÜBİTAK-TBAG (108T622) and Balıkesir University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Balıkesir University, Cagis, 10145, Balıkesir, Turkey

    Çiğdem Hopa, Mahir Alkan & Raif Kurtaran

  2. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Samsun, Turkey

    Canan Kazak & N. Burcu Arslan

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  1. Çiğdem Hopa
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  2. Mahir Alkan
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  3. Canan Kazak
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  4. N. Burcu Arslan
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Correspondence to Çiğdem Hopa.

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Hopa, Ç., Alkan, M., Kazak, C. et al. Iron(III) complex of a tridentate NNN type ligand: synthesis, X-ray structure, thermal analysis and voltammetric studies. Transition Met Chem 34, 403–407 (2009). https://doi.org/10.1007/s11243-009-9209-9

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