Skip to main content
SpringerLink
Log in

Synthesis and X-ray structural characterization of mono(aminophosphine) derivatives of molybdenum hexacarbonyl, Mo(CO)5L {L = P(NC5H10)3, P(Ph)(NC4H8O)2 or P(Ph){N(i-C3H7)2}(NC4H8O)}

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Equimolar reactions of molybdenum hexacarbonyl with tris(piperidino)phosphine (L1), bis(morpholino)(phenyl)phosphine (L2), and (Di-isopropylamino)(morpholino)(phenyl) phosphine (L3), which are examples of symmetrically and unsymmetrically substituted tertiary(amino)phosphines, afford the corresponding mono derivatives, Mo[P(NC5H10)3)](CO)5 (1), Mo[P(Ph)(NC4H8O)2](CO)5 (2), and Mo[P(Ph){N(i-C3H7)2}(NC4H8O)](CO)5 (3) in moderate yields as air stable crystalline solids. In the case of L1, some amount of trans-bis derivative, Mo[P(NC5H10)3)]2(CO)4 (4), was also isolated. X-ray structures of 1, 2, and 3 have been determined. Compounds 1 and 2 crystallize in the monoclinic system with space group P21/c, while 3 crystallizes in the triclinic system with space group Pī. While the Mo-P and Mo-Cax bond distances in these complexes are comparable with those of other P-C bonded phosphines, the presence of chiral phosphine seems to induce a relatively weaker interaction with the molybdenum center. Intermolecular hydrogen bonding is seen in compound 1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Cotton FA, Wilkinson G, Murillo CA, Bochman M (1999) Advanced inorganic chemistry. Wiley-Interscience, New York

    Google Scholar 

  2. Gilheany DG, Mitchell CM, Hartley FR (1990) The chemistry of organophosphorus compounds. Wiley, Chichester, p 151

    Google Scholar 

  3. Quin LD (2000) A guide to organophosphorus chemistry. Wiley, New York, p 375

    Google Scholar 

  4. Cotton FA, Hong B (1992) Prog Inorg Chem 40:179. doi:10.1002/9780470166413.ch3

    Article  CAS  Google Scholar 

  5. Tolman CA (1977) Chem Rev 77:313. doi:10.1021/cr60307a002

    Article  CAS  Google Scholar 

  6. Simpson MC, Cole-Hamilton DJ (1996) Coord Chem Rev 155:163. doi:10.1016/S0010-8545(96)90181-2

    Article  CAS  Google Scholar 

  7. Price SJ, Bowen RJ, Galettis P, Healy PC, McKeage MJ (1999) Coord Chem Rev 185:823. doi:10.1016/S0010-8545(99)00039-9

    Article  Google Scholar 

  8. Ainscough EW, Brodie AM, Burrell AK, Freeman GH, Jameson GB, Bowmaker GA, Hanna JV, Healy PC (2001) J Chem Soc Dalton Trans 144

  9. Mc Campbell TA, Kinkel BA, Miller SM, Helm ML (2006) J Chem Crystallogr 36:271. doi:10.1007/s10870-005-9022-z

    Article  CAS  Google Scholar 

  10. Blagborough TC, Davis R, Ivison P (1994) J Organomet Chem 467:85. doi:10.1016/0022-328X(94)88012-3

    Article  CAS  Google Scholar 

  11. Balakrishna MS, Prakasha TK, Siriwardane U, Hosmane NS, Krishnamurthy SS (1990) J Organomet Chem 390:203. doi:10.1016/0022-328X(90)85032-T

    Article  CAS  Google Scholar 

  12. Ardon M, Hogarth G, Oscroft DTW (2004) J Organomet Chem 689:2429. doi:10.1016/j.jorganchem.2004.04.030

    Article  CAS  Google Scholar 

  13. Bokaris EP (1997) Polym Bull 38(1):35. doi:10.1007/s002890050016

    Article  CAS  Google Scholar 

  14. Bokaris EP, Kosmas MK (1998) Polym Bull 41(1):21. doi:10.1007/s002890050328

    Article  CAS  Google Scholar 

  15. Brown TL, Lee KJ (1993) Coord Chem Rev 128:89. doi:10.1016/0010-8545(93)80025-Z

    Article  CAS  Google Scholar 

  16. Kubas GJ, Ryan RR, Swanson BI, Vergamini PJ, Wasserman HJ (1984) J Am Chem Soc 106(2):451. doi:10.1021/ja00314a049

    Article  CAS  Google Scholar 

  17. Wasserman HJ, Kubas GJ, Ryan RR (1986) J Am Chem Soc 108(9):2294. doi:10.1021/ja00269a027

    Article  CAS  Google Scholar 

  18. Bruns W, Kaim W, Waldhoer E, Krejcik M (1995) Inorg Chem 34:663. doi:10.1021/ic00107a021

    Article  CAS  Google Scholar 

  19. Ganesamoorthy C, Balakrishna MS, George PP, Mauge JT (2007) Inorg Chem 46:848. doi:10.1021/ic061883j

    Article  CAS  Google Scholar 

  20. Fei Z, Dyson PJ (2005) Coord Chem Rev 249:2056. doi:10.1016/j.ccr.2005.03.014

    Article  CAS  Google Scholar 

  21. Appleby T, Woollins JD (2002) Coord Chem Rev 235:121. doi:10.1016/S0010-8545(02)00182-0

    Article  CAS  Google Scholar 

  22. Luiz TA, Varghese B, Rao MNS (2007) Synth React Inorganic Met -Org Chem 37:669

    CAS  Google Scholar 

  23. Balakrishna MS, Suresh D, George PP, Mauge JT (2006) Polyhedron 25:3215. doi:10.1016/j.poly.2006.05.041

    Article  CAS  Google Scholar 

  24. Perrin DD, Armarego WLF, Perrin DR (1980) Purification of laboratory chemicals, 2nd edn. Oxford, Pergamon Press, New York

    Google Scholar 

  25. Romming C, Songstad J (1978) Acta Chem Scand A 32(8):689

    Article  Google Scholar 

  26. Jeffery GH, Bassett J, Mendham J, Denney RC (1989) Vogel’s textbook of quantitative chemical analysis, 5th edn. Longman Singapore

  27. Clardy JC, Kolpa RL, Verkade JG (1976) Phophorus Relat Group V Elem 4:133

    Google Scholar 

  28. Davies MS, Aroney MJ, Buys IE, Hambley TW, Calvert JL (1995) Inorg Chem 34:330. doi:10.1021/ic00105a051

    Article  CAS  Google Scholar 

  29. Cotton FA, Darensbourg DL, Isley WH (1981) Inorg Chem 20:578. doi:10.1021/ic50216a051

    Article  CAS  Google Scholar 

  30. Palcic JD, Baughman RG, Golynskiy MV, Frawley SB, Peters RG (2005) J Organomet Chem 690:534. doi:10.1016/j.jorganchem.2004.09.034

    Article  CAS  Google Scholar 

  31. Kane JC, Yap GPA, Rheingold AL, Wong EH (1999) Inorg Chim Acta 287:209. doi:10.1016/S0020-1693(98)00419-8

    Article  CAS  Google Scholar 

  32. Hirsivaara L, Guerricabeitia L, Haukka M, Suomalainen P, Laitinen RH, Pakkanen TA, Pursiainen J (2000) Inorg Chim Acta 307:47. doi:10.1016/S0020-1693(00)00190-0

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors thank IIT Madras for research fellowship. Sophisticated Analytical Instruments Facility (SAIF), IIT Madras is acknowledged for XRD and spectral facilities.

Author information

Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, India

    T. Arun Luiz, Adinarayana Doddi & M. N. Sudheendra Rao

  2. Sophisticated Analytical Instruments Facility, Indian Institute of Technology Madras, Chennai, 600036, India

    Babu Varghese

Authors
  1. T. Arun Luiz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Adinarayana Doddi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Babu Varghese
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. N. Sudheendra Rao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. N. Sudheendra Rao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arun Luiz, T., Doddi, A., Varghese, B. et al. Synthesis and X-ray structural characterization of mono(aminophosphine) derivatives of molybdenum hexacarbonyl, Mo(CO)5L {L = P(NC5H10)3, P(Ph)(NC4H8O)2 or P(Ph){N(i-C3H7)2}(NC4H8O)}. Transition Met Chem 33, 745–750 (2008). https://doi.org/10.1007/s11243-008-9106-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-008-9106-7

Keywords

Search

Navigation