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Hydrothermal synthesis and characterization of two novel tungstovanadophosphate derivatives

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Abstract

Two novel tungstovanadophosphate derivatives, namely [Fe(phen)3]2[PW VI8 VVV IV5 O42] · H2O (1) and [Fe(phen)3]2[PW9V3O40] (2), were synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, ESR, XPS, TGA, and single-crystal X-ray diffraction analysis. The crystal structure analyses reveal that the ‘mixed-addenda’ Keggin polyoxoanion in 1 is decorated with VO2+ units, such that four V atoms are disordered over eight metal sites; the anion in compound 2 has a typical Keggin structure with three V atoms disordered over 12 metal sites. The two compounds are ionic crystals with slightly different packing modes for the polyoxoanions and [Fe(phen)3]3+ cations. π–π stacking interactions between phen molecules, weak hydrogen bonding interactions between phen ligands and polyoxoanions, and electrostatic forces lead to an extended 3D supramolecular framework.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Feng-Xia Ma, Ya-Guang Chen, Dong-Mei Shi, Fan-Xia Meng & Hai-Jun Pang

  2. Basic Science Department, Jilin Agricultural Science and Technology College, Jilin, 132101, People’s Republic of China

    Feng-Xia Ma

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  1. Feng-Xia Ma
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  2. Ya-Guang Chen
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  3. Dong-Mei Shi
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Correspondence to Ya-Guang Chen.

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Ma, FX., Chen, YG., Shi, DM. et al. Hydrothermal synthesis and characterization of two novel tungstovanadophosphate derivatives. Transition Met Chem 33, 697–703 (2008). https://doi.org/10.1007/s11243-008-9099-2

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