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Kinetics of substitution at [tris(3,5-dimethylpyrazolyl)-hydroborato]molybdenum nitrosyl dihalides by alcohols and by aniline

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Abstract

The kinetics of substitution by alcohols and by aniline at [tris(3,5-dimethylpyrazolyl)hydroborato]molybdenum nitrosyl dihalides in toluene solution at 298.2 K and at atmospheric pressure are reported and interpreted in terms of an associative mechanism.

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Notes

  1. Ligand abbreviations: cp = cyclopentadienyl; bipy = 2,2′-bipyridyl.

  2. See e.g. reference [13].

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Acknowledgement

The authors are grateful for helpful comments from reviewers.

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Authors and Affiliations

  1. Chemistry Department, University of Leicester, Leicester, LE1 7RH, UK

    Saad Alshehri, John Burgess & Colin D. Hubbard

  2. 40, Tolethorpe Close, Oakham, Rutland, LE15 6GF, England

    Colin D. Hubbard

  3. School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK

    Christopher J. Jones & Amit K. Das

Authors
  1. Saad Alshehri
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  2. John Burgess
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  3. Colin D. Hubbard
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  4. Christopher J. Jones
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  5. Amit K. Das
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Correspondence to Colin D. Hubbard.

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Alshehri, S., Burgess, J., Hubbard, C.D. et al. Kinetics of substitution at [tris(3,5-dimethylpyrazolyl)-hydroborato]molybdenum nitrosyl dihalides by alcohols and by aniline. Transition Met Chem 33, 417–420 (2008). https://doi.org/10.1007/s11243-008-9058-y

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  • DOI: https://doi.org/10.1007/s11243-008-9058-y

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