Abstract
Two new salts, [oClBzTPP] +2 [Ni(mnt)2]2−(1) and [oClBzTPP]+[Ni(mnt)2]−(2) ([oClBzTPP]+ = 1-(2′-chlorobenzyl)triphenylphosphonium and mnt2− = maleonitriledithiolate) have been prepared and characterized by elemental analyses, UV, IR, MS spectra, single crystal X-ray diffraction, and magnetic susceptibility. The Ni ions of the Ni(mnt)2 anions for 1 and 2 exhibit the square-planar coordination geometry. The Ni(III) ions of 2 form a 1D zigzag alternating magnetic chain within a Ni(mnt) −2 column through Ni···S, S···S, or Ni···Ni interactions. The C–H···N, C–H···S, C–H···π hydrogen bonds or π···π stacking interactions play important roles in the molecular stabilizing and stacking of 1 and 2. Magnetic susceptibility measurements in the temperature range 1.8−300 K show that 2 exhibits diamagnetic behavior.
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References
Robertson N, Cronin L (2002) Coord Chem Rev 227:93
Nishijo J, Ogura E, Yamaura J, Miyazaki A, Enoki T, Takano T, Kuwatani Y, Iyoda M (2000) Solid State Commun 116:661
Pullen AE, Faulmann C, Pokhodnya KI, Cassoux P, Tokumoto M (1998) Inorg Chem 37:6714
Clemenson PI, Underhill AE, Hursthouse MB, Short RL (1988) J Chem Soc Dalton Trans 1689
Urichi M, Yakushi K, Yamashita Y, Qin J (1998) J Mater Chem 8:141
Robertson N, Bergemann C, Becher H, Agarwal P, Julian SR, Friend RH, Hatton NJ, Underhill AE, Kobayashi A (1999) J Mater Chem 9:1713
Nishijo J, Ogura E, Yamaura J, Miyazaki A, Enoki T, Takano T, Kuwatani Y, Iyoda M (2003) Synth Met 133–134:539
Coomber AT, Beljonne D, Friend RH, Brédas JL, Charlton A, Robertson N, Underhill AE, Kurmoo M, Day P (1996) Nature 380:144
Ni CL, Song DY, Meng QJ (2006) Chem Phys Lett 419:351
Ni CL, Yu LL, Yang LM (2006) Inorg Chim Acta 359:1383
Ni CL, Dang DB, Song Y, Gao S, Li YZ, Ni ZP, Tian ZF, Wen LL, Meng QJ (2004) Chem Phys Lett 396:353
Ni CL, Dang DB, Li YZ, Gao S, Ni ZP, Tian ZF, Meng QJ (2005) J Solid State Chem 178:100
Ni ZP, Ren XM, Ma J, Xie JL, Ni CL, Chen ZD, Meng QJ (2005) J Am Chem Soc 127:14330
Xie JL, Ren XM, Gao S, Zhang WW, Li YZ, Lu CS, Ni CL, Liu WL, Meng QJ, Yao YG (2003) Eur J Inorg Chem 2393
Ni CL, Li YZ, Dang DB, Song Y, P Ni Z, Meng QJ (2005) Inorg Chim Acta 358:2680
Ni CL, Li YZ, Dang DB, Ni ZP, Tian ZF, Yuan ZR, Meng QJ (2005) Inorg Chem Commun 8:105
Bulgarevich SB, Bren DV, Movshovic DY, Finocchiaro P, Failla S (1994) J Mol Struct 317:147
Davison A, Holm RH (1967) Inorg Synth 10:8
SHELXTL, Version 5.10. Structure Determination Software Programs, Bruker Analytical X-ray Systems, Inc. Madison, Wisconsin, USA (2000)
Yang SB, Ni CL (2006) Acta Cryst E62:m483
Liu MG, Ni CL (2006) Acta Cryst E62:m2445
Sahid H, Gopal D, Mihir KC (2007) J Mol Struct 837:190
Barooah N, Karmakar A, Sarma RJ, Baruah JB (2006) Inorg Chem Commun 9:1252
Schlapfer CW, Nakamoto K (1975) Inorg Chem 14(6):1138
Shupack SI, Billig E, Clark RJH, Williams R, Gray HB (1964) J Am Chem Soc 86:4594
Fujita W, Awaga K (1999) Science 286:261
Ren XM, Meng QJ, Yong Y, Hu CJ, Lu CS, Chen XY, Xue ZL (2002) Inorg Chem 41:5931
Ni CL, Li YZ, Dang DB, Gao S, Ni ZP, Tian ZF, Wen LL, Meng QJ (2005) Polyhedron 24:1669
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The authors thank the president’s science foundation of South China Agricultural University (No.K05096) for financial support of this work. The Center of Analysis and Determination of South China Agricultural University are acknowledged.
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Hou, Y., Zhou, J., Liu, X. et al. Syntheses, crystal structures, and properties of two salts based on Ni(mnt)2 (mnt2− = maleonitriledithiolate) anion and substituted triphenylphosphonium cation. Transition Met Chem 33, 411–416 (2008). https://doi.org/10.1007/s11243-008-9054-2
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DOI: https://doi.org/10.1007/s11243-008-9054-2