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A novel cation induced polymeric chain in Na8[{Cu(gly)2}2]{H2(H2W12O42)}] · 24H2O: hydrothermal synthesis, spectroscopic characterization and X-ray structure analysis

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Abstract

A novel bis(glycinato)copper(II)paradodecatungstate Na8[{Cu(gly)2}2]-{H2(H2W12O42)}] · 24H2O (1) has been synthesized under hydrothermal conditions. The crystal structure of 1 reveals an infinite one-dimensional chain along the [100] direction and is built from paradodecatungstate (H2W12O42)10− clusters joined through [Cu(gly)2] moieties. Parallel chains are interlinked by NaO6 octahedra to generate a two-dimensional network.

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Acknowledgment

M. Ali thanks UGC for financial support from the UGC Scheme of University with potential for excellence and UGC [32-247/2006(SR)], New Delhi.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Kolkata, 700 032, India

    Daipayan Dutta, Dipankar Maity & Mahammad Ali

  2. Department of Chemistry, University of Reading, Whiteknights, Reading, RG6 6AD, UK

    Michael G. B. Drew

  3. Solid State Physics Department, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, 700 032, India

    Swastik Mondal & Monika Mukherjee

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  1. Daipayan Dutta
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  2. Dipankar Maity
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Correspondence to Mahammad Ali.

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Dutta, D., Maity, D., Ali, M. et al. A novel cation induced polymeric chain in Na8[{Cu(gly)2}2]{H2(H2W12O42)}] · 24H2O: hydrothermal synthesis, spectroscopic characterization and X-ray structure analysis. Transition Met Chem 33, 347–351 (2008). https://doi.org/10.1007/s11243-007-9049-4

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  • DOI: https://doi.org/10.1007/s11243-007-9049-4

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