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The synthesis and characterization of a porphyrazine bearing aza-15-crown-5 moieties in the peripheral positions and its cobalt(II) complex

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Abstract

The synthesis of novel metal-free (H2-Pz) and metalloporphyrazines (MgPz and CoPz), peripherally substituted with eight aza-15-crown-5 moieties, is described. The novel compounds were characterized by elemental analysis, i.r, 1H and 13C-n.m.r, UV–vis and m.s. spectral data.

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Acknowledgment

This study was supported by the Research Fund of Karadeniz Technical University, project no: 2006.111.002.1 (Trabzon-Turkey).

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Authors and Affiliations

  1. Department of Chemistry, Karadeniz Technical University, Trabzon, 61080, Turkey

    Halit Kantekin, Elif Çelenk & Hülya Karadeniz

  2. Department of Chemistry, Giresun University, Giresun, Turkey

    Zekeriya Bıyıklıoğlu

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  1. Halit Kantekin
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  2. Elif Çelenk
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  3. Zekeriya Bıyıklıoğlu
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  4. Hülya Karadeniz
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Correspondence to Halit Kantekin.

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Kantekin, H., Çelenk, E., Bıyıklıoğlu, Z. et al. The synthesis and characterization of a porphyrazine bearing aza-15-crown-5 moieties in the peripheral positions and its cobalt(II) complex. Transition Met Chem 33, 189–193 (2008). https://doi.org/10.1007/s11243-007-9023-1

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  • DOI: https://doi.org/10.1007/s11243-007-9023-1

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