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Synthesis, crystal structure and magnetism study on novel one-dimensional Cu(II) coordination polymers with 2,5-dimethylpyrazine-1,4-dioxide as bridging ligand

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Abstract

A novel one-dimensional coordination polymer [Cu(μ 1,6-dmpzdo)(dmpzdo)2]·(ClO4)2 (dmpzdo = 2,5-dimethylpyrazine-1,4-dioxide) has been synthesized and its crystal structure determined by X-ray crystallography. In the complex each Cu1 atom is located in a square planar coordination environment with two oxygen atoms O2 and O2A from two dmpzdo terminal ligands, and two other oxygen atoms O3 and O3A from two μ 1,6-dmpzdo bridging ligands. The one-dimensional chain is constructed by the coordination of a μ 1,6-dmpzdo bridging ligand and Cu(II) ions. The data of the variable temperature (4–300 K) magnetic susceptibilities were fitted by using the one-dimensional chain fitting formula, which gave the magnetic coupling constants 2J = −98.88 cm−1.

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Authors and Affiliations

  1. Department of Chemistry, Shandong Normal University, Jinan, 250014, P. R. China

    Jing-Min Shi, Feng-Xia Zhang, Chang-Ju Wu & Lian-Dong Liu

  2. Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China

    Long Yi

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  1. Jing-Min Shi
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  2. Feng-Xia Zhang
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  3. Chang-Ju Wu
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  4. Lian-Dong Liu
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  5. Long Yi
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Correspondence to Jing-Min Shi.

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Shi, JM., Zhang, FX., Wu, CJ. et al. Synthesis, crystal structure and magnetism study on novel one-dimensional Cu(II) coordination polymers with 2,5-dimethylpyrazine-1,4-dioxide as bridging ligand. Transition Met Chem 31, 879–881 (2006). https://doi.org/10.1007/s11243-006-0077-2

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  • DOI: https://doi.org/10.1007/s11243-006-0077-2

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