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Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer: Na2[Co(1,4-napdc)2(DMF)2]

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Abstract

A new 3D inorganic–organic hybrid framework microporous material Na2Co(1,4-napdc)2(DMF)2(1,4-napdc =  napthalene-1,4-dicarboxylate), which is constructed by coordination of cobalt ion and sodium ions with napthalene-1,4-dicarboxylate and DMF, is synthesized under solvothermal conditions. Two bidentate-bridging and two chelate-bridged carboxylate link a cobalt (II) and two sodiums (I) to the dimer structure. The square grids constructed with the caged-laddered-shaped secondary building units (SBUs) built by Co–O–Na–O and Co–O–C–O bond and 1,4-napdc links stack over each other to generate infinite 3D networks, which have a microporous channel (11.05 × 11.05 Å2) along the crystallographic c-axis. The thermal stability of the compound was investigated by differential scanning calorimetric and thermogravimetric analysis. The complexes could be anticipated as potential heat-resistant energetic material.

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Authors and Affiliations

  1. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, P.R. China

    Rui-Feng Wu, Tong-Lai Zhang, Jian-Guo Zhang, Xiao-Jing Qiao, Li Yang & Jin-Yu Guo

  2. College of Chemical Engineering of Inner Mongolia University of Technology, Hohhot, 010051, P.R. China

    Rui-Feng Wu

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  1. Rui-Feng Wu
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  2. Tong-Lai Zhang
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  3. Jian-Guo Zhang
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  4. Xiao-Jing Qiao
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  5. Li Yang
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  6. Jin-Yu Guo
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Correspondence to Tong-Lai Zhang.

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Wu, RF., Zhang, TL., Zhang, JG. et al. Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer: Na2[Co(1,4-napdc)2(DMF)2]. Transition Met Chem 31, 874–878 (2006). https://doi.org/10.1007/s11243-006-0076-3

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  • DOI: https://doi.org/10.1007/s11243-006-0076-3

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