Skip to main content
SpringerLink
Log in

Chelation and Analytical Application of Thiosemicarbazides Toward Platinum(IV) Ions

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

N(1)H derivatives of ethyl- and phenyl-thiosemicarbazides have been prepared and identified so as to produce new complexes with H2PtCl6. The obtained complexes have been investigated by thermal, magnetic and spectral studies. They were found to be diamagnetic and to have an octahedral structure. The IR data reveal different modes of coordination for the investigated ligands. The thermal decomposition of some complexes ended with PtS2 as a final product. The formation of a green associate with 1-phenyl-4-ethylthiosemicarbazide (HPETS) was found suitable for the preconcentration and determination of Pt(IV). A simple and effective separation–determination procedure was achieved through the use of the flotation technique. The deprotonation constants of the ligands and the stability constants of the complexes formed in solution were evaluated by electrochemical methods, Methylthiosemicarbazide (HMTS) complexes were found to be the most stable in solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Y. Kang N. Yang S.O. Kang J. Ko (1997) Organometallics 16 5522 Occurrence Handle1:CAS:528:DyaK2sXntlejsLo%3D Occurrence Handle10.1021/om970660l

    Article  CAS  Google Scholar 

  2. D.X. West J.K. Swearingen J.V. Martinez S.H. Ortega A.K. El-Sawaf F. Meurs ParticleVan A. Castineiras I. Garcia E. Bermejo (1999) Polyhedron 18 2919 Occurrence Handle1:CAS:528:DyaK1MXnt1WhsL4%3D Occurrence Handle10.1016/S0277-5387(99)00210-7

    Article  CAS  Google Scholar 

  3. P. Tarasconi S. Capacchi G. Pelosi M. Cornia R. Albertini A. Bonati P.P. Dall’ Aglio P. Lunghi S. Pinelli (2000) Bioorg. Med. Chem. 8 157 Occurrence Handle1:CAS:528:DC%2BD3cXht1GrtL0%3D Occurrence Handle10.1016/S0968-0896(99)00260-6

    Article  CAS  Google Scholar 

  4. A. Kumar S. Chandra (1993) Synth. React. Inorg. Met.- Org. Chem. 23 671 Occurrence Handle1:CAS:528:DyaK3sXktl2lsrs%3D

    CAS  Google Scholar 

  5. J. Ackerman P.E. Franwick M.A. Green E. John W.E. Running J.K. Swearingen J.W. Webb D.X. West (1999) Polyhedron 18 2759 Occurrence Handle1:CAS:528:DyaK1MXmslert7s%3D Occurrence Handle10.1016/S0277-5387(99)00173-4

    Article  CAS  Google Scholar 

  6. S.E. Ghazy M.A. Kabil A.A. El-Asmy Y.E. Sherif (1996) Anal. Lett. 29 1215 Occurrence Handle1:CAS:528:DyaK28XjsVWjtr8%3D

    CAS  Google Scholar 

  7. A.A. El-Asmy M.M. Mostafa (1983) J. Coord. Chem 12 291 Occurrence Handle1:CAS:528:DyaL3sXks1eiurY%3D

    CAS  Google Scholar 

  8. A.A. El-Asmy (1989) Bull. Soc. Chem. Fr. 2 171

    Google Scholar 

  9. E. Khalifa A.A. El-Asmy K.M. Ibrahim M.M. Mostafa (1986) Synth. React. Inorg. Met. Org. Chem. 16 1305 Occurrence Handle1:CAS:528:DyaL2sXhtlSltr0%3D

    CAS  Google Scholar 

  10. A.A. El-Asmy T.Y. Al-Ansi R.R. Amin M. Mounir (1986) Polyhedron 9 2029 Occurrence Handle10.1016/S0277-5387(00)84032-2

    Article  Google Scholar 

  11. N.M. El-Metwally R.M. El-Shazly I.M. Gabr A.A. El-Asmy (2005) Spectrochimica Acta (A) 61 1113 Occurrence Handle1:STN:280:DC%2BD2M7htFGhtQ%3D%3D Occurrence Handle10.1016/j.saa.2004.06.027

    Article  CAS  Google Scholar 

  12. N.M. El-Metwally I.M. Gabr A.M. Shallaby A.A. El-Asmy (2005) J. Coord. Chem. 58 1145 Occurrence Handle1:CAS:528:DC%2BD2MXpsFCqur0%3D Occurrence Handle10.1080/00958970500155771

    Article  CAS  Google Scholar 

  13. H.M. Irving and H.S. Rossotti, J. Chem. Soc., 2904 (1954).

  14. A.I. Vogel (1994) A Text Book of Quantitative Inorganic Analysis Longmans London

    Google Scholar 

  15. W.J. Jeary (1971) Coord. Chem. Rev. 7 81 Occurrence Handle10.1016/S0010-8545(00)80009-0

    Article  Google Scholar 

  16. A.A. El-Asmy (1988) J. Chin. Chem. Soc. 35 29 Occurrence Handle1:CAS:528:DyaL1MXmvVCrsw%3D%3D

    CAS  Google Scholar 

  17. S.J. Swamy K. Bhaskar (1999) Ind. J. Chem. 38A 961 Occurrence Handle1:CAS:528:DC%2BD3cXht1WhtA%3D%3D

    CAS  Google Scholar 

  18. A.A. Abo-Hussen A.A. Emara (2004) J. Coord. Chem. 57 973 Occurrence Handle10.1080/00958970412331272412

    Article  Google Scholar 

  19. M. Jouad A. Riou M. Allain M.A. Khan G.M. Bouet (2001) Polyhedron 20 67 Occurrence Handle1:CAS:528:DC%2BD3MXpvFOhtw%3D%3D Occurrence Handle10.1016/S0277-5387(00)00598-2

    Article  CAS  Google Scholar 

  20. I. Mostafa, M.Sc. Thesis, Mansoura University, Egypt. 1991

  21. G. Ponticelli A. Spanu M.T. Cocco V. Onnis (1999) Transition Met. Chem. 24 370 Occurrence Handle1:CAS:528:DyaK1MXksVSrsLw%3D Occurrence Handle10.1023/A:1006997515302

    Article  CAS  Google Scholar 

  22. L. Petrilli F. Tarli G. Chiozzini C. Riccuecci (1997) Polyhedron 16 275 Occurrence Handle1:CAS:528:DyaK28Xnt1ems7k%3D Occurrence Handle10.1016/0277-5387(96)00249-5

    Article  CAS  Google Scholar 

  23. K. Mukkanti R.P. Singh (1987) Transition Met. Chem. 12 299 Occurrence Handle1:CAS:528:DyaL1cXhsl2jsb0%3D Occurrence Handle10.1007/BF01024017

    Article  CAS  Google Scholar 

  24. A.W. Coats J.P. Redfern (1964) Nature 20 68

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, Egypt

    Ahmed A. El-Asmy & Nashwa M. El-Metwally

  2. Chemistry Department, Faculty of Science, Taiz University, Taiz, Yemen

    G. A. Al-Hazmi

Authors
  1. Ahmed A. El-Asmy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nashwa M. El-Metwally
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. A. Al-Hazmi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ahmed A. El-Asmy.

Rights and permissions

Reprints and permissions

About this article

Cite this article

El-Asmy, A.A., El-Metwally, N.M. & Al-Hazmi, G.A. Chelation and Analytical Application of Thiosemicarbazides Toward Platinum(IV) Ions. Transition Met Chem 31, 673–680 (2006). https://doi.org/10.1007/s11243-006-0046-9

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-006-0046-9

Keywords

Search

Navigation