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Three new copper(II)–nickel(II) heterodinuclear complexes with the N,N′-bis(2-pyridyl-ethyl)oxamide dianion. Syntheses, spectra, and magnetic properties

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Abstract

Three new Cu(II)–Ni(II) heterodinuclear complexes: [Cu(PMoxd)Ni(phen)2](ClO4)2 (1), [Cu(PMoxd)Ni(NO2-phen)2](ClO4)2 (2), [Cu(PEoxd)Ni(Me2-bpy)2](ClO4)2 (3), [where Cu(PMoxd)=N,N′-bis(pyridyl-methyl)oxamidatocopper(II), Cu(PExod)=N,N′-bis(2-pyridyl-ethyl)oxamidatocopper(II), phen=1,10-phenanthroline and NO2-phen=5-nitro-1,10-phenanthroline and bpy=2,2′-bipyridine] were prepared and characterized by i.r. and electronic spectra, and by magnetic properties. The magnetic analysis was carried out by means of the theoretical expression of the magnetic susceptibility deduced from the spin Hamiltonian H=−2JS1S2, leading to J=−70.83 cm−1 (1); −56.23 cm−1 (2); −57.30 cm−1 (3), indicating a weak antiferromagnetic spin–exchange interaction between Cu(II) and Ni(II) ions within three complexes.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, China

    Yan Ouyang, Bin Liu, Qing-Lun Wang, Dai-Zheng Liao, Zong-Hui Jiang & Shi-Ping Yan

  2. Tianjin Medicinal College, 300052, China

    Bin Liu

  3. State Key Laboratory of Structure Chemistry, Fujian Institute of Research on Structure of Matter, Chinese Academy of Science, Fuzhou Fujian, 350002, China

    Dai-Zheng Liao

  4. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, China

    Zong-Hui Jiang

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  1. Yan Ouyang
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  2. Bin Liu
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  3. Qing-Lun Wang
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  4. Dai-Zheng Liao
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  5. Zong-Hui Jiang
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  6. Shi-Ping Yan
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  7. Bin Liu
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  8. Dai-Zheng Liao
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  9. Zong-Hui Jiang
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Correspondence to Dai-Zheng Liao.

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Ouyang, Y., Liu, B., Wang, QL. et al. Three new copper(II)–nickel(II) heterodinuclear complexes with the N,N′-bis(2-pyridyl-ethyl)oxamide dianion. Syntheses, spectra, and magnetic properties. Transition Met Chem 30, 460–463 (2005). https://doi.org/10.1007/s11243-005-2660-3

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  • DOI: https://doi.org/10.1007/s11243-005-2660-3

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