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Azido derivatives of dinuclear copper(II) and 1D polynuclear nickel(II) complexes containing an unsymmetrical bidentate amine: synthesis, crystalline architecture, and magnetic behavior

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Abstract

Dinuclear copper(II) complex [Cu2(L)2(μ2-1,1-N3)2(N3)2] (1) with double μ1,1-azido bridges and polynuclear nickel(II) complex [Ni(L)(μ2-1,1-N3)(μ2-1,3-N3)]n (2) with alternate double μ1,1-azido and μ1,3-azido bridges [L = 1-amino-2-(dimethylamino)ethane, N −3  = azide ion] have been synthesized and were characterized by physicochemical and spectroscopic methods. X-ray structural analysis revealed that each Cu(II) center of 1 adopts a distorted square-pyramidal geometry with a CuN5 chromophore ligated through two N atoms of L, two N atoms of double bridging (μ1,1-N3), and one N atom of terminal azide ion. On the other hand, each Ni(II) center around the asymmetric unit of 2 adopts a distorted octahedral geometry with a NiN6 chromophore ligated through two N atoms of L, two N atoms of double μ1,1-N3, and two N atoms of double μ1,3-N3 bridges. The adjacent nickel centers are connected to alternate double μ1,1-N3 and double μ1,3-N3 bridges, affording a one-dimensional (1D) polymeric chain structure. Temperature-dependent magnetic susceptibility measurements evidenced a dominant antiferromagnetic interaction between the metal centers of both complexes 1 and 2.

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Acknowledgements

The work is financially supported by the Department of Science and Technology, Government of India, by grant SR/S1/IC-13/2010 to C.A.

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Authors and Affiliations

  1. Department of Chemistry, Kabi Nazrul College, Murarai, Birbhum, West Bengal, 731 219, India

    Habibar Chowdhury

  2. Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Parco Area delle Scienze 17/A, 43124, Parma, Italy

    Corrado Rizzoli

  3. Department of Education, The University of Burdwan, Golapbag, Burdwan, West Bengal, 713104, India

    Chandan Adhikary

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  1. Habibar Chowdhury
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  2. Corrado Rizzoli
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Correspondence to Chandan Adhikary.

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Chowdhury, H., Rizzoli, C. & Adhikary, C. Azido derivatives of dinuclear copper(II) and 1D polynuclear nickel(II) complexes containing an unsymmetrical bidentate amine: synthesis, crystalline architecture, and magnetic behavior. Transit Met Chem 46, 139–147 (2021). https://doi.org/10.1007/s11243-020-00430-8

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