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Structural and magnetic studies on mono- and polynuclear chromium ascorbate complexes

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An Erratum to this article was published on 17 February 2007

Abstract

Polynuclear chromium ascorbate complexes were isolated and physicochemically analyzed in a comparative manner with their mononuclear analog (1). Characterization by elemental analysis, electronic, vibrational, 13C-n.m.r and mass spectroscopies, and variable temperature magnetic susceptibility studies, allowed structural proposals for the binuclear, [Cr2(μ-OH)2(H2O)(C6H7O6)3(OH)] · 4H2O (2), and trinuclear, [Cr3(μ-O)3(H2O)6(C6H7O6)3] · 4 H2O (3) complexes. The pseudo-octahedral CrIII centers were suggested to be connected through hydroxo bridges in (2) and in (3) by oxo bridges forming a hexocyclic ring.

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Authors and Affiliations

  1. Department of Chemistry,, Hacettepe University, Beytepe Campus, 06800, Ankara, Turkey

    Birgül Zümreoglu-Karan, Ahmet N. Ay & Canan Ünaleroglu

  2. Department of Physics Engineering, Hacettepe University, Beytepe Campus, 06800, Ankara, Turkey

    Tezer Firat

  3. Institut für Chemie u. Biochemie, E. M. A. Universität Greifswald, D-17489, Greifswald, Germany

    Thomas Ristau & Wolfgang Jabs

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  1. Birgül Zümreoglu-Karan
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An erratum to this article is available at http://dx.doi.org/10.1007/s11243-006-9100-x.

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Zümreoglu-Karan, B., Ay, A.N., Ünaleroglu, C. et al. Structural and magnetic studies on mono- and polynuclear chromium ascorbate complexes. Transition Met Chem 30, 451–459 (2005). https://doi.org/10.1007/s11243-005-1035-0

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