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Ruthenium(II) complexes containing triphenylphosphine/triphenylarsine and bidentate Schiff bases derived from 2-hydroxy-1-naphthaldehyde and primary amines

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Abstract

The synthesis and characterisation of some new hexa-coordinated Schiff base complexes of the type [RuCl(CO)(EPh3)(B)(L)] (E = P or As; B = PPh3 or AsPh3 or py or pip; L = anion of the Schiff bases derived from 2-hydroxy-1-naphthaldehyde and aniline, 4-chloroaniline or 2-methylaniline) are reported. I.r., electronic, 1H-n.m.r, 31P-n.m.r. spectra, catalytic activity and antibacterial activity of the complexes are discussed. An octahedral structure has been tentatively proposed for all the complexes.

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References

  1. M.J. Clarke, Coord. Chem. Rev., 232, 69 (2002).

    Google Scholar 

  2. R. Karvembu, S. Hemalatha, R. Prabhakaran and K. Natarajan, Inorg. Chem. Commun., 6, 486 (2003).

    Google Scholar 

  3. E.M. Jouad, G. Larcher, M. Allain, A. Riou, G.M. Bouet, M.A. Khan and X.D. Thanh, J. Inorg. Biochem., 86, 565 (2001).

    PubMed  Google Scholar 

  4. P. Bindu, M.R.P. Kurup and T.R. Satyakeerty, Polyhedron, 18, 321 (1999).

    Google Scholar 

  5. N.C. Kasuga, K. Sekino, C. Koumo, N. Shimada, M. Ishikawa and K. Nomiya, J. Inorg. Biochem., 84, 55 (2001).

    PubMed  Google Scholar 

  6. M.B. Ferrari, S. Capacchi, G. Pelosi, G. Reffo, P. Tarasconi, R. Albertini, S. Pinalli and P. Lunghi, Inorg. Chim. Acta, 286, 134 (1999).

    Google Scholar 

  7. G. Coates, P. Calalghan, J.J. McGarvey, J.M. Kelly, L. Jacquet and A. Kirsch-De Mesmaeker, J. Mol. Str., 598, 15 (2001).

    Google Scholar 

  8. R. Karvembu, C. Jayabalakrishnan, N. Dharmaraj, S.V. Renukadevi and K. Natarajan, Transition Met. Chem., 27, 631 (2002).

    Google Scholar 

  9. N. Ahmed, J.J. Levison, S.D. Robinson and M.F. Uttley, Inorg. Synth., 15, 48 (1974).

    Google Scholar 

  10. S. Gopinathan, I.R. Unny, S.S. Deshpande and C. Gopinathan, Indian J. Chem., 25A, 1015 (1986).

    Google Scholar 

  11. R.A. Sanchez-Delgade, W.Y. Lee, S.R. Choi, Y. Cho and M.J. Jun, Transition Met. Chem., 16, 241 (1991).

    Google Scholar 

  12. B. Khera, A.K. Sharma and N.K. Kaushik, Polyhedron, 2, 1177 (1983).

    Google Scholar 

  13. A.I. Vogal, Text Book of Practical Organic Chemistry, 5th ed., Longman, London, 1989.

    Google Scholar 

  14. S.N. Pal and S. Pal, Polyhedron, 22, 867 (2003).

    Google Scholar 

  15. S.N. Pal and S. Pal, J. Chem. Soc. Dalton Trans., 2102 (2002).

  16. R. Ramesh, N. Dharmaraj, R. Karvembu and K. Natarajan, Indian J. Chem., 39A, 1079 (2000).

    Google Scholar 

  17. R. Karvembu and K. Natarajan, Polyhedron, 21, 219 (2002).

    Google Scholar 

  18. A.B.P. Lever, Inorganic Electronic Spectroscopy., Elsevier, New York, 1984.

    Google Scholar 

  19. V. Chinnusamy and K. Natarajan, Synth. React. Inorg. Met.-Org. Chem., 23, 889 (1993).

    Google Scholar 

  20. G. Muthusamy and K. Natarajan, Indian J. Chem., 34A, 4909 (1995).

    Google Scholar 

  21. R. Karvembu and K. Natarajan, Polyhedron, 21, 1721 (2002).

    Google Scholar 

  22. N. Dharmaraj and K. Natarajan, Transition Met. Chem., 26, 105 (2001).

    Google Scholar 

  23. A.M. El-Hendavey, A.H. Al-Kubaisi and H.A. Al-Madfa, Polyhedron, 16, 3039 (1997).

    Google Scholar 

  24. D. Chatterjee, A. Mitra and B.C. Roy, J. Mol. Cat. A: Chem., 161, 17 (2000).

    Google Scholar 

  25. J.Y. Kim, M.J. Jun and W.Y. Lee, Polyhedron, 15, 3787 (1996).

    Google Scholar 

  26. C.H. Colins and P.M. Lyne, Microbial Methods, University Park Press Baltimore, p. 422, 1970.

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Authors and Affiliations

  1. Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641 020, India

    Kugalur P. Balasubramanian & Vaiapuri Chinnusamy

  2. Department of Chemistry, Bharathiar University, Coimbatore, 641 046, India

    Ramasamy Karvembu & Karuppannan Natarajan

Authors
  1. Kugalur P. Balasubramanian
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  2. Vaiapuri Chinnusamy
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  3. Ramasamy Karvembu
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  4. Karuppannan Natarajan
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Balasubramanian, K.P., Chinnusamy, V., Karvembu, R. et al. Ruthenium(II) complexes containing triphenylphosphine/triphenylarsine and bidentate Schiff bases derived from 2-hydroxy-1-naphthaldehyde and primary amines. Transition Metal Chemistry 29, 644–648 (2004). https://doi.org/10.1007/s11243-004-4993-8

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  • DOI: https://doi.org/10.1007/s11243-004-4993-8

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