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Influence of the Structure and Composition of H3–2xMnxPMo12O40 AND (NH4)3–2xMnxPMo12O40 Heteropolycompounds on their Catalytic Properties in the Process of Cyclohexanone Oxidation with Hydrogen Peroxide

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Theoretical and Experimental Chemistry Aims and scope

Catalytic properties of two series of Keggin-type heteropolycompounds, H3–2xMnxPMo12O40 and (NH4)3–2xMnxPMo12O40 (x = 0.25-1.5), have been studied in the process of oxidation of cyclohexanone and/or cyclohexanol to adipic acid, using 30% hydrogen peroxide, in the absence of organic solvent. The main products and by-products have been identified by means of GC-MS analysis. The highest yields of adipic acid are found in the case of H1.5Mn0.75PMo12O40 and (NH4)2Mn0.5PMo12O40 compounds.

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Authors and Affiliations

  1. Laboratoire de Chimie du Gaz Naturel, Faculte de Chimie, Universite des Sciences et de la Technologie Houari Boumediene, Alger, Algeria

    A. Boumechhour, S. Benadji & C. Rabia

  2. Centre de Recherche scientifique et technique en Analyses Physico-Chimiques, Tipaza, Algeria

    A. Boumechhour

  3. Laboratoire de Chimie Appliquee et de Genie Chimique, Universite Mouloud-Mammeri, Tizi-Ouzou, Algeria

    T. Mazari & L. Dermeche

Authors
  1. A. Boumechhour
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  2. S. Benadji
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  3. T. Mazari
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  4. L. Dermeche
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  5. C. Rabia
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Correspondence to A. Boumechhour.

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Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 58, No. 4, pp. 248-258, July-August, 2022.

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Boumechhour, A., Benadji, S., Mazari, T. et al. Influence of the Structure and Composition of H3–2xMnxPMo12O40 AND (NH4)3–2xMnxPMo12O40 Heteropolycompounds on their Catalytic Properties in the Process of Cyclohexanone Oxidation with Hydrogen Peroxide. Theor Exp Chem 58, 276–289 (2022). https://doi.org/10.1007/s11237-022-09745-2

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  • DOI: https://doi.org/10.1007/s11237-022-09745-2

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