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Nanocomposite of Polyaniline with Partially Oxidized Graphene as the Transport Layer of Light-Emitting Polymer Diodes

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Feasibility has been demonstrated for the use of the interpolymer complex of polyaniline with poly(2-acrylamide-2-methyl-1-propanesulfonic acid) (PAni·PAMPSA) and its nanocomposite with partially oxidized graphene (PAni·PAMPSA/POGr) as a material for hole transport layers in the manufacture of polymer light-emitting diodes (PLED). A study was carried out on the functional characteristics of such PLED, which were compared with those of traditional PLED made with poly(3,4-ethylenedioxythiophene) doped with polystyrenesulfonate anions (PEDOT/PSS). The PLED made with PAni·PAMPSA/POGr nanocomposites were shown to have better functional characteristics, namely, current density, brightness, current and luminous efficiency, than for the analogous heterostructures derived from the pure PAni·PAMPSA interpolymer complex. The PAni·PAMPSA/POGr nanocomposite may be used instead of PEDOT/PSS in the manufacture of efficient organic optoelectronic devices.

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This work was supported by the State Target Science and Technology Program “Development and application of energy saving diode light sources and lighting systems” (Project 1.2.4.2) and the Program of Joint Ukrainian–Russian Research Projects of the National Academy of Sciences of Ukraine and Russian Basic Research Fund (Projects 23-03-12(U) and 12-03-90435-Ukr_a).

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    O. Yu. Posudievsky, O. A. Khazieieva, V. G. Koshechko & V. D. Pokhodenko

  2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii Prospekt, 31, Building 4, Moscow, 119991, Russian Federation

    D. A. Lypenko, O. L. Gribkova, A. A. Nekrasov & A. V. Vannikov

  3. V. E. Lashkaryov Institute of Semiconductor Physics, National Academy of Sciences of Ukraine, Prospekt Nauky, 41, Kyiv, 03028, Ukraine

    V. M. Sorokin

Authors
  1. O. Yu. Posudievsky
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  2. D. A. Lypenko
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  3. O. A. Khazieieva
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  4. O. L. Gribkova
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  5. A. A. Nekrasov
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  6. A. V. Vannikov
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  7. V. M. Sorokin
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  8. V. G. Koshechko
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  9. V. D. Pokhodenko
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Correspondence to O. Yu. Posudievsky.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 50, No. 2, pp. 94-100, March-April, 2014.

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Posudievsky, O.Y., Lypenko, D.A., Khazieieva, O.A. et al. Nanocomposite of Polyaniline with Partially Oxidized Graphene as the Transport Layer of Light-Emitting Polymer Diodes. Theor Exp Chem 50, 96–102 (2014). https://doi.org/10.1007/s11237-014-9352-z

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  • DOI: https://doi.org/10.1007/s11237-014-9352-z

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