The influence of the promoter HCl on the kinetic process of the solution of spongy titanium in phosphoric acid has been investigated. A new one-step ecologically pure waste-free method for the utilization of titanium waste into a valuable product – TiP2O7 – has been developed. The methods for preparation of pigment and adsorbent with improved physical and chemical properties on its base were designed. The influence of the physico-chemical parameters of titanium pyrophosphate on its catalytic activity in the partial oxidation of methane. ethane, and propane has been studied.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
L. M. Antipin, S. Yu. Teleshov, V. V. Zelentsov, et al., “Method for the preparation of joint oxides of phosphorus and titanium,” SSSR Patent 72427, CI C 01 B 25/12, Publ. 1977, Bull. No. 12.
S. V. Zolotavina, A. P. Shtin, and A. K. Sharova, Investigation of Physico-Chemical Properties of Compounds of Rare High Melting Elements, Izd. AN SSSR, Sverdlovsk (1970), pp. 108–114.
V. I. Gomonai, V. A. Drozdenko, K. Yu. Sekeresh, and N. P. Golub, “Method for processing the titanium products,” Ukrainian Patent 53510, CI7 C 23 G 1/02, C 23 F 3/03, 1/16, C 09 K 13/04, Publ. Oct. 17, 2005, Bull. No. 10.
P. Stasczuk, T. Danielkiewicz, and J. Klinowski, IV Polish-Ukrainian Symp. “Theoretical and experimental studies of interfacial phenomena and their technological applications,” Lublin, Sept 1–3, 1999, p. 51.
N. P. Golub, Regularities of Catalytic Oxidation of Ethane on Acid Catalysts [in Ukrainian], Author’s Abstract of Dissertation in competition for the academic degree of Candidate of the Chemical Sciences, Uzhgorod (1996).
V. I. Gomonai, V. A. Drozdenko, and K. Yu. Sekeresh, “Method for preparation of titanium pyrophosphate,” Author’s Certificate SSSR 1738754, CI C 01 B 25/42, Publ. Febr. 8, 1992, Bull. No. 21.
R. L. Diller, Table of Interatomic Distances [in Russian], Nedra, Moscow (1966), Vol. 2.
I. I. Nebola, Solution of X-ray Powder Photographs [in Russian], Moscow, Metallurgiya (1975).
L. I. Mirkin, Handbook of X-ray Structural Analysis of Polycrystals [in Russian], Ya. Umanskii (ed.), Gos. Izd. Fiz.-Mat. Lit., Moscow (1961).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir, Moscow (1982).
Atlas of Infrared Spectra of Phosphates. Pyrophosphates, Nauka, Moscow (1981).
G. I. Golodets, Catalysis and Catalysts, Naukova Dumka, Kiev (1980), pt.18, pp. 66–75.
K. Yu. Szekeresh, Study of Physico-Chemical Properties and Catalytic Activity of Phosphate Catalysts in the Process of Methane Oxidation, Author’s Abstract of Dissertation in competition for the academic degree of Candidate of the Chemical Sciences, Uzhhorod (1978).
V. I. Gomonay, Physico-Chemical Bases of the Choice of Heterogeneous Catalysts for the Partial Oxidation of n-Alkanes, Author’s Abstract of Dissertation in competition for the academic degree of Candidate of the Chemical Sciences, Kiev (1990).
N. Golub, V. Gomonay, P. Gomonay, and P. Szekeresh, Adsorp. Sci. Technol., 17, No. 5, 403–406 (1999).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 49, No. 1, pp. 49–54, January-February, 2013.
Rights and permissions
About this article
Cite this article
Golub, N.P., Gomonay, V.I. & Szekeresh, K.Y. Influence of the Surface Characteristics of TiP2O7 on Its Catalytic Activity in the Oxidation of Hydrocarbons. Theor Exp Chem 49, 52–57 (2013). https://doi.org/10.1007/s11237-013-9294-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11237-013-9294-x