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EFFECT OF THE SUPPORT NATURE ON THE PHYSICOCHEMICAL PROPERTIES OF PLATINUM CATALYSTS FOR AMMONIA OXIDATION

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Abstract

Platinum catalysts prepared by incipient wetness impregnation of different supports (TiO2, WO3/TiO2, CeO2, Al2O3, zeolite ZSM-5) are tested in the ammonia oxidation reaction (TPR–NН3+О2) and characterized by a combination of physicochemical (powder XRD, TEM, XPS) and kinetic (TPR–H2, TPD–NH3) techniques. On the surface of all catalysts, platinum is present in the highly dispersed form (average particle size <1.5 nm), providing the activity for ammonia oxidation above 150 °C. In the temperature range 150-250 °C, the main oxidation products are nitrous oxide and molecular nitrogen whereas NOx oxides start to form at T > 250 °C. The highest catalytic activity is observed when platinum is supported on TiO2 promoted with tungsten. The introduction of tungsten modifies the acidity of the surface and affects the redox properties of platinum catalysts. The role of the support is found to be the stabilization of oxidized or reduced platinum forms on the surface, thus determining the total activity in the ammonia oxidation reaction.

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Funding

The work was supported by the Russian Science Foundation, grant No. 18-43-06201, 3.09.2018.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    D. A. Svintsitskiy, E. M. Slavinskaya, L. S. Kibis, A. I. Stadnichenko, E. A. Fedorova, O. A. Stonkus, E. V. Korneeva, A. V. Romanenko & A. I. Boronin

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  1. D. A. Svintsitskiy
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  2. E. M. Slavinskaya
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Correspondence to A. I. Boronin.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 4, pp. 639-654.https://doi.org/10.26902/JSC_id71154

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Svintsitskiy, D.A., Slavinskaya, E.M., Kibis, L.S. et al. EFFECT OF THE SUPPORT NATURE ON THE PHYSICOCHEMICAL PROPERTIES OF PLATINUM CATALYSTS FOR AMMONIA OXIDATION. J Struct Chem 62, 598–612 (2021). https://doi.org/10.1134/S0022476621040120

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