Skip to main content
SpringerLink
Log in

Reactivity of the H2O2/B(OH)3/HO- system in the decomposition of 4-nitrophenyl esters of diethylphosphonic and diethylphosphoric acids

  • Published:
Theoretical and Experimental Chemistry Aims and scope

The kinetics of the decomposition of 4-nitrophenyl diethylphosphonate and 4-nitrophenyl diethyl phosphate by the H2O2/B(OH)3/HO– system with wide variation of the pH and the initial concentrations of H2O2 and B(OH)3 (water, 25°C) was studied. Additions of boric acid either weakly accelerate the reaction or retard it, depending on the ratio of the initial concentrations of hydrogen peroxide and boric acid and on the nature of the substrate. The peroxoborate anions (HO)3BOOH–, (HO)2B(OOH) –2 , and (HO)3BOOB(OH) 2–3 anions generated by this system do not affect the decomposition rate of the substrates. In both substrates linear relationships were found between the observed rate constants k and the concentrations of peroxide anion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1

Similar content being viewed by others

Notes

  1. The equilibrium constant was determined for μ = 0.1 M and 25°C. (In the case of K 2 the ionic strength was maintained with NaClO4, and in the case of K 3, K 4, and K 5 with KNO3.)

References

  1. A. F. Popov, Pure Appl. Chem., 80, No. 7, 1381–1397 (2008).

    Article  CAS  Google Scholar 

  2. A. Latt, I. Riko-Latt, E. Perez, et al., Zh. Ros. Khim. Obshch. im. D. I. Mendeleeva, 51, No. 6, 36–43 (2007).

    Google Scholar 

  3. D. M. Davies, M. E. Deary, K. Quill, and R. A. Smith, Chem. Eur. J., 11, 3552–3558 (2005).

    Article  CAS  Google Scholar 

  4. B. Balagam and D. E. Richardson, Inorg. Chem., 47, No. 3, 1173–1178 (2008).

    Article  CAS  Google Scholar 

  5. V. L. Lobachev, G. P. Zimtseva, Ya. V. Matvienko, and E. S. Rudakov, Teor. Éksp. Khim., 43, No. 1, 38–42 (2007). [Theor. Exp. Chem., 43, No. 1, 44–49 (2007) (English translation).]

    Google Scholar 

  6. L. N. Vakhitova, K. V. Matvienko, N. A. Taran, et al., Zh. Organ. Khim., 47, No. 7, 951–960 (2011).

    Google Scholar 

  7. D. E. Richardson, H. Yao, K. M. Frank, and D. A. Bennett, J. Am. Chem. Soc., 122, No. 8, 1729–1739 (2000).

    Article  CAS  Google Scholar 

  8. V. L. Lobachev, V. A. Savelova, T. M. Prokop’eva, Teor. Éksp. Khim., 40, No. 3, 157–161 (2004). [Theor. Exp. Chem., 40, No. 3, 161–166 (2004) (English translation).]

    Google Scholar 

  9. T. M. Prokop’eva, Yu. S. Sadovskii, V. A. Savelova, et al., Ukr. Khim. Zh., 77, No. 1, 54–60 (2011).

    Google Scholar 

  10. M. C. Durrant, D. M. Davies, and M. E. Deary, Org. Biol. Chem., 9, 7249–7254 (2011).

    Article  CAS  Google Scholar 

  11. Yu. S. Simanenko, A. F. Popov, T. M. Prokop’eva, et al., Zh. Organ. Khim., 38, No. 9, 1341–1353 (2002).

    Google Scholar 

  12. C. J. Adams and I. E. Clark, Polyhedron, 2, No. 7, 673–675 (1983).

    Article  CAS  Google Scholar 

  13. R. Pizer and C. Tihal, Inorg. Chem., 26, No. 21, 3639–3642 (1987).

    Article  CAS  Google Scholar 

  14. J. Flanagan, W. P. Griffith, R. D. Powell, and A. P. West, J. Chem. Soc. Dalton Trans., 1651–1655 (1989).

  15. N. Ingri, Acta Chem. Scand., 16, No. 2, 439–448 (1962).

    Article  CAS  Google Scholar 

  16. A. K. Babko and I. V. Pyatnitskii, Quantitative Analysis [in Russian], Vysshaya Shkola, Moscow (1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Vul. R. Luxemburg, 70, Donets’k, 83114, Ukraine

    Yu. S. Sadovskii, T. N. Solomoichenko, T. M. Prokop’eva, Zh. P. Piskunova, N. G. Razumova, B. V. Panchenko & A. F. Popov

Authors
  1. Yu. S. Sadovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. N. Solomoichenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. M. Prokop’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zh. P. Piskunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. G. Razumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. V. Panchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. F. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. M. Prokop’eva.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 48, No. 3, pp. 152-158, May-June, 2012.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sadovskii, Y.S., Solomoichenko, T.N., Prokop’eva, T.M. et al. Reactivity of the H2O2/B(OH)3/HO- system in the decomposition of 4-nitrophenyl esters of diethylphosphonic and diethylphosphoric acids. Theor Exp Chem 48, 163–171 (2012). https://doi.org/10.1007/s11237-012-9256-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11237-012-9256-8

Key words

Search

Navigation