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Physical and chemical problems of the creation of photostable converters of light energy on the basis of dyed polymers

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Theoretical and Experimental Chemistry Aims and scope

The main factors affecting the degradation of dyed polymeric matrices by the action of light (conversion of light energy into thermal energy, electron phototransfer, population of triplets, aggregation of dyes, oxidation–reduction processes, interaction with oxygen, including singlet) are analyzed and classified. Their dependence on the structure of the dyes, the nature of the polymer, and the method of dyeing of the latter is examined. Criteria for the creation of lightfast dyed matrices are formulated. Special attention is directed to contemporary light-sensitive materials in which the dye is covalently bonded to the polymer and to organic–inorganic compositions based on them.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Vul. Murmans’ka, 5, Kyiv, 02094, Ukraine

    A. A. Ishchenko

  2. Taras Shevchenko Kyiv National University, Vul. Volodymyrs’ka, 64, Kyiv, 01033, Ukraine

    G. P. Grabchuk

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 45, No. 3, pp. 133-155, May-June, 2009.

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Ishchenko, A.A., Grabchuk, G.P. Physical and chemical problems of the creation of photostable converters of light energy on the basis of dyed polymers. Theor Exp Chem 45, 143–167 (2009). https://doi.org/10.1007/s11237-009-9078-5

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