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Effect of the extent of reduction of V2O5 on the adsorption of propylene and the oxidative dehydrogenation of propane to give propylene on V2O5 and V2O5/TiO2-SiO2

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Abstract

An increase in the propylene output in the oxidative dehydration of propane on V2O5/TiO2-SiO2 was observed after prior reduction of V2O5 in the reaction mixture to V2O4, which reduces the destructive chemisorption of propylene. A low titanium dioxide content in TiO2-SiO2 hinders the deep reduction of V2O5 to V2O3, which reduces the conversion of propane.

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Authors and Affiliations

  1. National Aviation University, Prospekt Kosmonavta Komarova, 1, Kyiv, 03058, Ukraine

    A. V. Red’kina & Yu. V. Belokopytov

  2. Institute for Sorption and Problems in Endoecology, National Academy of Sciences of Ukraine, Vul. Generala Naumova, 13, Kyiv, 05165, Ukraine

    N. D. Konovalova & K. N. Khomenko

Authors
  1. A. V. Red’kina
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  2. Yu. V. Belokopytov
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  3. N. D. Konovalova
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  4. K. N. Khomenko
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Correspondence to A. V. Red’kina.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 43, No. 6, pp. 373–378, November–December, 2007.

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Red’kina, A.V., Belokopytov, Y.V., Konovalova, N.D. et al. Effect of the extent of reduction of V2O5 on the adsorption of propylene and the oxidative dehydrogenation of propane to give propylene on V2O5 and V2O5/TiO2-SiO2 . Theor Exp Chem 43, 405–410 (2007). https://doi.org/10.1007/s11237-007-0050-y

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  • DOI: https://doi.org/10.1007/s11237-007-0050-y

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