Abstract
A study was carried out on the conditions of formation of highly crystalline, superparamagnetic, nanosized oxides, MII Fe III2 O4 and γ-Fe2O3 (4.9–11.7 nm) by the thermal decomposition of complexes [MFe2O(CH3CO2)6(H2O)3] (M = Mn, Fe, Co, Ni) in tetraethylene glycol. The presence of surfactants leads to a decrease in the size and size distribution of the nanoparticles formed, while the use of microwave radiation significantly reduces the time for formation of the nanocrystalline oxides. The magnetic measurements showed ferrimagnetic ordering in the nanoparticles studied and their superparamagnetic behavior.
Similar content being viewed by others
References
U. Jeong, X. Teng, Y. Wang, et al., Adv. Mater., 19, 33–60 (2007).
S. P. Gubin, Yu. A. Koksharov, G. B. Khomutov, et al., Usp. Khim., 74, No. 6, 539–574 (2005).
D. Astruc, F. Lu, and J. R. Aranzaes, Angew. Chem. Int. Ed., 44, 7852–7872 (2005).
A.-H. Lu, E. L. Salabas, and F. Schüth, Angew. Chem. Int. Ed., 46, 1222–1244 (2007).
X. Wang and Y. Li, Pure Appl. Chem., 78, No. 1, 45–64 (2006).
X.-M. Lina and A. C. S. Samia, J. Magn. Magn. Mat., 305, 100–109 (2006).
K. S. Gavrilenko, T. V. Mironyuk, V. G. Il’in, et al., Teor. Éksp. Khim., 38, No. 2, 110–115 (2002). [Theor. Experim. Chem., 38, No. 2, 118–124 (2002) (Engl. Transl.).]
S. S. Berdonosov and D. G. Berdonosova, Khim. Tekhnol., No. 3, 2–8 (2000).
A. B. Blake, A. Yavari, W. E. Hatfield, et al., J. Chem. Soc., Dalton Trans., 2509–2520 (1985).
L. Meesuk, U. A. Jayasooriya, and R. D. Cannon, J. Am. Chem. Soc., 109, No. 7, 2009–2016 (1987).
O. M. Gloer (Ed.), Practical Methods in Electron Microscopy [in Russian], Mashinostroenie, Leningrad (1980).
R. S. Guter and B. V. Ovchinksii, Elements of Numerical Analysis and Mathematical Treatment of Experimental Results [in Russian], Fizmatgiz, Moscow (1962).
D. Caruntu, Y. Remond, N. H. Chou, et al., Inorg. Chem., 41, 6137–6146 (2002).
A. N. Pilyankevich and A. M. Klimovitskii, Electron Microscopy, Tekhnika, Kiev (1976).
JCPDS-ICCD, PCPDFWIN Software (version 2.4), June, 2003.
T. Hyeon, S. S. Lee, J. Park, et al., J. Am. Chem. Soc., 123, 12798–12801 (2001).
K. S. Gavrilenko, Synthesis and Physicochemical Properties of Homo-and Heteropolynuclear μ 3-Oxocarboxylates [in Ukrainian], Dissertation in competition for the academic degree of Candidate of Chemical Sciences, Kyiv (2002).
N. Moumen and M. P. Pileni, J. Phys. Chem., 100, 1867–1873 (1996).
E. Kang and J. Park, J. Phys. Chem. B, 108, 13932–13935 (2004).
Author information
Authors and Affiliations
Corresponding author
Additional information
__________
Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 43, No. 5, pp. 323–329, September–October, 2007.
Rights and permissions
About this article
Cite this article
Vasilenko, I.V., Gavrilenko, K.S., Kotenko, I.E. et al. Effect of formation conditions on the structure, morphology and magnetic properties of nanosized MIIFe III2 O4 ferrites (M = Mn, Co, Ni) and Fe2O3 . Theor Exp Chem 43, 353–360 (2007). https://doi.org/10.1007/s11237-007-0043-x
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11237-007-0043-x