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A new Cu(II) three-dimensional network with 4,4′-oxybis benzoic acid: structural diversity, EPR, and magnetism

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Abstract

The copper derivative {[Cu4(oba)4(H2O)4]∙H2O}n (1) has been hydro(solvo)thermally synthesized by combining flexible 4,4′-oxybis benzoic acid (oba) and divalent copper nitrate. As a result of the potential coordination modes of carboxylate oxygens from the oba ligand, the aforementioned complex leads to the formation of an interesting 3D framework, as evidenced by single-crystal X-ray diffractometry. Concerning the topology in 1, the dimers [Cu2C4O8] are nodes of a 5-fold 4-connected uninodal net of the type lvt, with point symbol {42.84} and vertex symbol [4.4.84.84.88.88]. The encapsulation of the copper coordination polymer displays a moderate luminescent property. On temperature-dependent magnetic study, it reveals that the magnetic behaviour of 1 can be associated to a strong antiferromagnetic coupling between the two Cu(II) ions.

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Acknowledgements

AD would like to thank the Ministry of Science and Technology, Taiwan, for the financial assistance. We wish to thank Dr. Chiara Massera, Dipartimento di Chimica, Universitá degli Studi di Parma, Parma, Italy, for valuable discussion on X-ray crystallography.

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Authors and Affiliations

  1. Department of Chemistry, National Changhua University of Education, Changhua, 50058, Taiwan

    Amitabha Datta

  2. Institute of Chemistry, Academia Sinica, Nankang, Taipei, 115, Taiwan

    Amitabha Datta, Kuheli Das & Sandeep B. Mane

  3. Dipartimento di Chimica e Farmacia, Università di Sassari, Via Vienna 2, I-07100, Sassari, Italy

    Eugenio Garribba

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  1. Amitabha Datta
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Datta, A., Das, K., Mane, S.B. et al. A new Cu(II) three-dimensional network with 4,4′-oxybis benzoic acid: structural diversity, EPR, and magnetism. Struct Chem 29, 553–561 (2018). https://doi.org/10.1007/s11224-017-1052-6

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