Abstract
“Do cement nanotubes exist?” is a question that has recently been asked. The answer is yes, they do exist. The evidence is in the literature, in tens of papers showing in detail chemical garden-type tubes in cement from the nanoscale upwards that were published in the 1970s and 1980s. Here, we present a nano-review of the literature.
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References
Double DD, Hellawell A (1976) The hydration of Portland cement. Nature 261:486
Double DD, Hellawell A (1977) The solidification of cement. Sci Am 237:82
Double DD, Hellawell A, Perry SJ (1978) The hydration of Portland cement. Proc R Soc A 359:435–451
Birchall JD, Howard AJ, Bailey JE (1978) On the hydration of Portland cement. Proc R Soc A 360:445–453
Jennings HM, Pratt PL (1979) An experimental argument for the existence of a protective membrane surrounding Portland cement during the induction period. Cem Concr Res 9:501–506
Barnes P, Ghose A, Mackay AL (1980) Cement tubules—another look. Cem Concr Res 10:639–645
Double DD (1983) New developments in understanding the chemistry of cement. Philos Trans R Soc A 310:53–66
Lasic DD, Pintar MM, Blinc R (1988) Are proton NMR observations supportive of the osmotic model of cement hydration? Philos Mag Lett 58:227–232
Mitchell LD, Prica M, Birchall JD (1996) Aspects of Portland cement hydration studied using atomic force microscopy. J Mater Sci 31:4207–4212
Clark SM, Morrison GR, Shib WD (1999) The use of scanning transmission X-ray microscopy for the real-time study of cement hydration. Cem Concr Res 29:1099–1102
Barge LM, Cardoso SSS, Cartwright JHE, Cooper GJT, Cronin L, De Wit A, Doloboff IJ, Escribano B, Goldstein RE, Haudin F, Jones DEH, Mackay AL, Maselko J, Pagano JJ, Pantaleone J, Russell MJ, Sainz-Díaz CI, Steinbock O, Stone DA, Tanimoto Y, Thomas NL (2015) From chemical gardens to chemobrionics. Chem Rev 115:8652–8703
Coatman RD, Thomas NL, Double DD (1980) Studies of the growth of “silicate gardens” and related phenomena. J Mater Sci 15: 2017–2026
Cartwright JHE, García-Ruiz JM, Novella ML, Otálora F (2002) Formation of chemical gardens. J Colloid Interface Sci 256:351–359
Thouvenel-Romans S, Steinbock O (2003) Oscillatory growth of silica tubes in chemical gardens. J Am Chem Soc 125:4338–4341
Stone DA, Goldstein RE (2004) Tubular precipitation and redox gradients on a bubbling template. Proc Natl Acad Sci USA 101:11537–11541
Manzano H, Enyashin AN, Dolado JS, Ayuela A, Frenzel J, Seifert G (2012) Do cement nanotubes exist? Adv Mater 24:3239
Bullard JW, Jennings HM, Livingston RA, Nonat A, Scherer GW, Schweitzer JS, Scrivener KL, Thomas JJ (2011) Mechanisms of cement hydration. Cem Concr Res 41:1208–1223
Double DD (1978) An examination of the hydration of Portland cement by electron microscopy. Silic Ind 11:233–246
Fonseca PC, Jennings HM (2010) The effect of drying on early-age morphology of C–S–H as observed in environmental SEM. Cem Concr Res 40:1673–1680
Thouvenel-Romans S, van Saarloos W, Steinbock O (2004) Silica tubes in chemical gardens: radius selection and its hydrodynamic origin. Europhys Lett 67:42–48
Stone DA, Lewellyn B, Baygents JC, Goldstein RE (2005) Precipitative growth templated by a fluid jet. Langmuir 21:10916–10919
Thomas NL (1987) Corrosion problems in reinforced concrete: why accelerators of cement hydration usually promote corrosion of steel. J Mater Sci 22:3328–3334
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Cardoso, S.S.S., Cartwright, J.H.E., Steinbock, O. et al. Cement nanotubes: on chemical gardens and cement. Struct Chem 28, 33–37 (2017). https://doi.org/10.1007/s11224-016-0811-0
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DOI: https://doi.org/10.1007/s11224-016-0811-0