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Synthesis and characterization of a three-dimensional framework built up of paradodecatungstate-B clusters and transition metals as linkers

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Abstract

A novel paradodecatungstate compound, namely [Na2(H2O)10][Cu4(H2O)12(H2W12O42)]·15H2O (1) has been synthesized by convenient aqueous solution method and structurally characterized by single-crystal X-ray diffraction, IR spectra, elemental analysis, thermogravimetric analysis, and differential thermal analysis. Single-crystal X-ray diffraction reveals that in compound 1, the [H2W12O42]10− anions are connected via divalent copper cation as purely inorganic linker to form a three-dimensional structural network. In addition, compound 1 exhibits strong photoluminescent emission at room temperature.

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Acknowledgments

The authors are thankful for the financial support from the Science and Technology Development Foundation of Jilin Province (201215171, 201201105).

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Authors and Affiliations

  1. Jilin Institute of Chemical Technology, Jilin, 132022, People’s Republic of China

    Xiaoshu Qu, Yanyan Yang, Feifei Zhang & Xiaoyang Yu

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  1. Xiaoshu Qu
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  2. Yanyan Yang
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  3. Feifei Zhang
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  4. Xiaoyang Yu
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Correspondence to Xiaoshu Qu.

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Qu, X., Yang, Y., Zhang, F. et al. Synthesis and characterization of a three-dimensional framework built up of paradodecatungstate-B clusters and transition metals as linkers. Struct Chem 23, 1867–1872 (2012). https://doi.org/10.1007/s11224-012-9994-1

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  • DOI: https://doi.org/10.1007/s11224-012-9994-1

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