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Synthesis and characterization of high-dimensional structure based on paradodecatungstate clusters and sodium–aminoacetic acid complex subunits

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Abstract

An organic–inorganic hybrid material based on paradodecatungstate building blocks and sodium–aminoacetic acid complex subunits,{Na10(H3N–CH2–COO)2[H2W12O42]}·28H2O (1), have been synthesized under mildly acidic conditions. This compound was characterized by single-crystal X-ray diffraction, elemental analysis, IR and UV–visible spectroscopies, and cyclic voltammetry. The compound crystallizes in the triclinic space group P-1 with a = 11.879(2) Å, b = 12.706(2) Å, c = 13.067(2) Å, α = 74.11(3)°, β = 79.71(3)°, γ = 65.95(3)°, V = 1727.2(5) Å3, and Z = 1. The crystal structure consists of infinite 2D layers constructed from [H2W12O42]10− clusters and sodium–aminoacetic acid complexes; adjacent layers are further joined by the complex units and sodium cations to yield a three-dimensional network.

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Acknowledgment

This work was supported by the Ministry of Higher Education and Scientific Research of Tunisia.

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Authors and Affiliations

  1. Laboratoire des Matériaux et Cristallochimie (LMC), Institut Supérieur des Sciences Appliquées et Technologie, Avenue El Mourouj, 5111, Mahdia, Tunisia

    Sana Chaalia, Brahim Ayed & Amor Haddad

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  1. Sana Chaalia
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  2. Brahim Ayed
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  3. Amor Haddad
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Correspondence to Sana Chaalia.

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Chaalia, S., Ayed, B. & Haddad, A. Synthesis and characterization of high-dimensional structure based on paradodecatungstate clusters and sodium–aminoacetic acid complex subunits. Struct Chem 22, 167–174 (2011). https://doi.org/10.1007/s11224-010-9701-z

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  • DOI: https://doi.org/10.1007/s11224-010-9701-z

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