Skip to main content
SpringerLink
Log in

Solvothermal synthesis and structures of three novel heterometallic microporous coordination polymers assembled from 2-hydroxy-nicotinic acid

  • Original Research
  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

Three novel heterometallic microporous coordination polymers {M(Hnico)3M′} n (1, M = Co, M′ = K; 2, M = Ni, M′ = K; 3, M = Co, M′ = Na, Hnico is the anion of 2-hydroxy-nicotinic acid, where the proton is transferred from the phenolate hydroxy group to the nitrogen atom of imine pyridine ring) were synthesized by hydrothermal reaction between M(Ac)2·4H2O, M′OH and a multifunctional organic aromatic H2nico ligand and characterized by IR spectrum, elemental analysis, raman spectrum and the single crystal X-ray diffractions. In complexes 1–3, the M2+ ions linked three different Hnico ligand formed [M(Hnico)3]− subunit which further interlinked the six-coordination M′+ cation constructed 3D network. The network topology of 1–3 can be simplified a rare 3D (4,4)-connected (41263) net.

Graphical Abstract

Three novel heterometallic polymers {M(Hnico)3M′} n (1, M = Co, M΄ = K; 2, M = Ni, M΄ = K; 3, M = Co, M΄ = Na, Hnico is the anion of 2-Hydroxy-nicotinic acid) were synthesized. The complexes display a rare 3D (4,4)-connected (41263) net topology and formed 3D porous compounds with 22.6%, 22.1% and 20.4% porosity factor for 1–3, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Wu CD, Hu A, Zhang L, Lin WJ (2005) J Am Chem Soc 127:8940

    Article  CAS  Google Scholar 

  2. Beauvais LG, Shores MP, Long JR (2000) J Am Chem Soc 122:2763

    Article  CAS  Google Scholar 

  3. Albrecht M, Lutz M, Spek AL, Koten GV (2000) Nature 406:970

    Article  CAS  Google Scholar 

  4. Lee EY, Jang SY, Suh MP (2005) J Am Chem Soc 127:6374

    Article  CAS  Google Scholar 

  5. Uemura K, Kitagawa S, Knodo M, Fukui K, Kitaura R, Chang HC, Mizutani T (2002) Chem Eur J 8:3587

    Article  Google Scholar 

  6. Dybtsev DN, Chun H, Yoon SH, Kim D, Kim K (2004) J Am Chem Soc 126:1308

    Article  Google Scholar 

  7. Ma LF, Wang LY, Huo XK, Wang YY, Fan YT, Wang JG, Chen SH (2008) Cryst Growth Des 8:620

    Article  CAS  Google Scholar 

  8. Yaghi OM, Rowsell JLC (2006) J Am Chem Soc 128:1304

    Article  Google Scholar 

  9. Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM (2003) Science 300:1127

    Article  CAS  Google Scholar 

  10. Horike S, Matsuda R, Tanaka D, Mizuno M, Endo K, Kitagawa S (2006) J Am Chem Soc 128:4222

    Article  CAS  Google Scholar 

  11. Kubota Y, Takata M, Matsuda R, Kitaura R, Kitagawa S, Kato K, Sakata M, Kobayashi TC (2005) Angew Chem Int Ed 44:920

    Article  CAS  Google Scholar 

  12. Liu CS, Shi XS, Li JR, Wang JJ, Bu XH (2006) Cryst Growth Des 6:656

    Article  Google Scholar 

  13. Zhao B, Gao HL, Chen XY, Cheng P, Shi W, Liao DZ, Yan SP, Jiang ZH (2006) Chem Eur J 12:149

    Article  CAS  Google Scholar 

  14. Min KS, Suh MP (2000) J Am Chem Soc 122:6834

    Article  CAS  Google Scholar 

  15. Yaghi OM, Li H (1996) J Am Chem Soc 118:295

    Article  CAS  Google Scholar 

  16. Zhang SH, Song Y, Liang H, Zeng MH (2009) CrystEngComm 11:865

    Article  Google Scholar 

  17. Zhang SH, Zhou YL, Sun XJ, Wei LQ, Zeng MH, Liang H (2009) J Solid State Chem 182:2991

    Article  CAS  Google Scholar 

  18. Yang J, Yue Q, Li GD, Cao JJ, Li GH, Chen JS (2006) Inorg Chem 45:2857

    Article  CAS  Google Scholar 

  19. Ma BQ, Zhang DS, Gao S, Jin TZ, Yan CH (2000) Angew Chem Int Ed 39:3644

    CAS  Google Scholar 

  20. Ma LF, Wang LY, Wang YY, Batten SR, Wang JG (2009) Inorg Chem 48:915

    Article  CAS  Google Scholar 

  21. Zou RQ, Sakurai H, Xu Q (2006) Angew Chem Int Ed 45:2542

    Article  CAS  Google Scholar 

  22. Li P, Liu HM, Lei XG, Huang XY, Olson DH, Turro NJ, Li J (2003) Angew Chem Int Ed 42:542

    Article  Google Scholar 

  23. Seo JS, Whang D, Lee H, Jun SI, Oh J, Jeon Y, Kim K (2000) Nature 404:982

    Article  CAS  Google Scholar 

  24. Subramanian S, Zaworotko MJ (1994) Coord Chem Rev 137:357

    Article  CAS  Google Scholar 

  25. Zhang SH, Zeng MH, Liang H (2008) Chin J Struct Chem 27:785

    Google Scholar 

  26. Zhang SH, Jiang YM, Liu ZM (2008) J Coord Chem 61:1927

    Article  CAS  Google Scholar 

  27. Wei YQ, Yu YF, Wu KC (2008) Cryst Growth Des 8:2087

    Article  CAS  Google Scholar 

  28. Caradoc-Davies PL, Hanton LR (2001) Chem Commun 1098

  29. Quintal SMO, Nogueira HIS, Felix V, Drew MGB (2002) Polyhedron 21:2783

    Article  CAS  Google Scholar 

  30. Ma CL, Li Ql, Zhang RF (2009) Inorg Chim Acta 362:2937

    Article  CAS  Google Scholar 

  31. Gu XJ, Xue Df (2007) CrystEngComm 9:471

    Article  CAS  Google Scholar 

  32. Wen DC, Liu SX (2007) Chin J Struct Chem 26:1281

    CAS  Google Scholar 

  33. Yao YW, Cai Q, Kou HZ, Li HD, Wang D, Yu RB, Chen YF, Xing XR (2004) Chem Lett 33:1270

    Article  CAS  Google Scholar 

  34. Lehaire ML, Scopelliti R, Herdeis L, Polborn K, Mayer P, Severin K (2004) Inorg Chem 43:1609

    Article  CAS  Google Scholar 

  35. Siemens SAINT (1996) Area detector control and integration software. Siemens Analytiacl X-ray instruments Inc, Madison, WI, USA

    Google Scholar 

  36. Sheldrick GM (1997) SHELXL97 and SHELXTL software reference manual, version 5.1. Brucker AXS Inc, Madison, WI, USA

    Google Scholar 

  37. Sheldrick GM (1996) SADABS. Program for empirical absorption correction of area detector data. University of Göttingen, Germany

    Google Scholar 

  38. Soares-Santos PCR, Nogueira HIS, Rocha J, Félix V, Drew MGB, Sá Ferreira RA, Carlos LD, Trindade T (2003) Polyhedron 22:3529

    Article  CAS  Google Scholar 

  39. Anson CE, Klopper W, Li JS, Ponikiewski L, Rothenberger A (2006) Chem Eur J 12:2032

    Article  CAS  Google Scholar 

  40. Zhang SH, Jiang YM, Xiao Y, Zhou ZY (2003) Chin J Inorg Chem 19:517

    CAS  Google Scholar 

  41. Dolomanov OV, Blake AJ, Champness NR, Schröder MJ (2003) J Appl Crystallogr 36:1283

    Article  CAS  Google Scholar 

  42. Hajba L, Mink J, Kühn FE, Goncalves IS (2006) Inorg Chim Acta 359:4741

    Article  CAS  Google Scholar 

  43. Dong Y, DiSalvo FJJ (2006) J Solid State Chem 179:1363

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is financially supported by the Young Science Foundation of Guangxi Province of China (No: 0832085), Guangxi Key Laboratory for Advance Materials and New Preparation Technology (No: 0842003-25), Startup foundation for Dr of Guilin University of Technology.

Author information

Authors and Affiliations

  1. College of Chemistry and Bioengineering, Guilin University of Technology (Key Laboratory of Nonferrous and Materials Processing Technology, Ministry of Education), Guilin, 541004, People’s Republic of China

    Shu Hua Zhang, Chao Feng & Yin Guang Wang

  2. Department of Chemistry and Chemical Engineering, Guangxi Normal University (Key Laboratory of Medicinal Chemical Resources and Molecular Engineering), Guilin, 541004, People’s Republic of China

    Hua Hong Zou

  3. Department College of Enviromental Science and Engineering, Guilin University of Technology (Guangxi Key Laboratory of Environmental Engineering, Protection and Assessment), Guilin, 541004, People’s Republic of China

    Yu Xiao

Authors
  1. Hua Hong Zou
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shu Hua Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu Xiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chao Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yin Guang Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shu Hua Zhang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 339 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zou, H.H., Zhang, S.H., Xiao, Y. et al. Solvothermal synthesis and structures of three novel heterometallic microporous coordination polymers assembled from 2-hydroxy-nicotinic acid. Struct Chem 22, 135–140 (2011). https://doi.org/10.1007/s11224-010-9684-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-010-9684-9

Keywords

Search

Navigation