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Synthesis, spectroscopic studies, and crystal structure of 2,6-diacetylpyridinediphenylhydrazone perchlorate and its complexing ability toward the lanthanides

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Abstract

2,6-diacetylpyridinediphenylhydrazone perchlorate was prepared and characterized by spectroscopic (IR, ESI–MS, UV–Vis, 1H NMR) and analytical data and its crystal structure was determined by single X-ray analysis. The lanthanum(III), praseodymium(III), and neodymium(III) perchlorate complexes of 2,6-diacetylpyridinediphenylhydrazone were prepared in a direct reaction of the ligand with appropriate metal perchlorates. The spectroscopic and analytical data indicate 1:2 metal to ligand stoichiometry. In all the complexes the hydrazones act as monodeprotonated terdentate NNN donor chelators. The same lanthanum(III) complex was also obtained in a one-step condensation reaction between 2,6-diacetylpyridine and phenylhydrazine in the presence of lanthanum(III) perchlorate.

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Acknowledgments

This work was supported by the Ministry of Science and Higher Education (grant NN204 0317 33).

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Authors and Affiliations

  1. Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland

    Wanda Radecka-Paryzek, Maciej Kubicki & Emilia Luks

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  1. Wanda Radecka-Paryzek
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  2. Maciej Kubicki
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  3. Emilia Luks
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Correspondence to Wanda Radecka-Paryzek.

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Dedicated to Professor Adam Bartecki on the occasion of his 90th birthday.

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Radecka-Paryzek, W., Kubicki, M. & Luks, E. Synthesis, spectroscopic studies, and crystal structure of 2,6-diacetylpyridinediphenylhydrazone perchlorate and its complexing ability toward the lanthanides. Struct Chem 21, 299–304 (2010). https://doi.org/10.1007/s11224-009-9532-y

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