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A two-dimensional ladder-type network in the 2:1 co-crystal of 1,2,5-thiadiazole-3,4-dicarboxylic acid and 4,4′-bipyridine

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Abstract

The crystal structure of the 2:1 co-crystal of 1,2,5-thiadiazole-3,4-dicarboxylic acid and 4,4′-bipyridine, (C4H2N2O4S)2·C10H8N2, has been determined by X-ray diffraction at the monoclinic space group C2/c with cell parameters of a = 21.388(7) Å, b = 6.735(2) Å, c = 14.877(5) Å, β = 110.431(3)°, and Z = 4. There are one molecule of thiadiazole and a half molecule of bipyridine in the asymmetric unit. The dihedral angle between the pyridine ring planes is 40.5(3)°. Two intramolecular O–H···N [2.730(7) Å] and O–H···O [2.433(6) Å] hydrogen bonds are observed in the thiadiazole molecule. In the crystal structure, the molecules form a unique two-dimensional ladder-type network linked by intermolecular O–H···N [2.704(4) Å] hydrogen bonds and S···O [3.100(5) Å] heteroatom interactions.

Index Abstract

In the crystal structure of the title co-crystal, the molecules form a unique two-dimensional ladder-type network linked by intermolecular O–H···N hydrogen bonds and S···O heteroatom interactions.

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Acknowledgments

The authors thank the Instrument Center of Institute for Molecular Science, for the X-ray structure analysis.

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Authors and Affiliations

  1. Institute for Molecular Science, Myodaiji, Okazaki, 444-8585, Japan

    Masaaki Tomura

  2. Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Nagatsuta, Midori-ku, Yokohama, 226-8502, Japan

    Yoshiro Yamashita

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  1. Masaaki Tomura
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  2. Yoshiro Yamashita
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Correspondence to Masaaki Tomura.

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Tomura, M., Yamashita, Y. A two-dimensional ladder-type network in the 2:1 co-crystal of 1,2,5-thiadiazole-3,4-dicarboxylic acid and 4,4′-bipyridine. Struct Chem 21, 107–111 (2010). https://doi.org/10.1007/s11224-009-9529-6

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  • DOI: https://doi.org/10.1007/s11224-009-9529-6

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