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Polymeric and monomeric dipicolinate complexes with 4-hydroxymethyl pyridine: spectral, structural, thermal and electrochemical characterization

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Abstract

Polymeric copper(II), [Cu(μ-dpc)(μ-4-hymp)] n (1), and monomeric nickel(II), [Ni(dpc)(4-hymp)(H2O)2]·H2O (2), (dpc: dipicolinate, 4-hymp: 4-hydroxymethyl pyridine), dipicolinate complexes have been prepared and characterized by spectroscopic (IR, UV–Vis, EPR), thermal (TG/DTA), X-ray diffraction technique and electrochemical methods. In both the dipicolinate complexes, the dpc dianion acts as a tridentate ligand. In polymeric copper(II) complex, the 4-hymp and dpc ligands adopt a bridging position between the Cu(II) centers, forming the elongated octahedral geometry. The polymeric chains are linked to one another via O–H···O hydrogen bond interactions, forming the 3-D polymeric structure. The Ni(II) ion is bonded to dpc ligand through pyridine N atom together with one O atom of each carboxylate group, two aqua ligands and N pyridine atom of 4-hymp, forming the distorted octahedral geometry. The Ni(II) complexes are connected to one another via O–H···O hydrogen bonds, forming R 24 (18) motifs in 2-D pattern. The powder EPR spectra of copper(II) complex have indicated that the paramagnetic center is in rhombic symmetry with the Cu2+ ion having distorted octahedral geometry. IR and UV–Vis spectroscopes all agree with the observed crystal structure.

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Authors and Affiliations

  1. Department of Physics, Faculty of Arts and Sciences, Ondokuzmayıs University, 55139, Kurupelit, Samsun, Turkey

    İbrahim Uçar & Ahmet Bulut

  2. Department of Chemistry, Faculty of Arts and Sciences, Ondokuzmayıs University, 55139, Kurupelit, Samsun, Turkey

    İclal Bulut

  3. Department of Chemistry, Faculty of Arts and Sciences, Gaziosmanpasa University, Taşlıçiftlik, 60240, Tokat, Turkey

    Ahmet Karadağ

Authors
  1. İbrahim Uçar
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  2. İclal Bulut
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  3. Ahmet Bulut
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  4. Ahmet Karadağ
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Correspondence to İbrahim Uçar.

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Uçar, İ., Bulut, İ., Bulut, A. et al. Polymeric and monomeric dipicolinate complexes with 4-hydroxymethyl pyridine: spectral, structural, thermal and electrochemical characterization. Struct Chem 20, 825–838 (2009). https://doi.org/10.1007/s11224-009-9475-3

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  • DOI: https://doi.org/10.1007/s11224-009-9475-3

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