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Thermal behavior of trehalose dihydrate (T h) and β-anhydrous trehalose (T β) by in-situ laboratory parallel-beam X-ray powder diffraction

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Abstract

Thermal behaviors of trehalose dihydrate (T h) and β-anhydrous trehalose (T β) have been investigated by in-situ laboratory parallel-beam X-ray powder diffraction. Data indicate that both phases show essentially the same volume expansion but expansion of the anhydrous form is markedly anisotropic due to the features of the hydrogen-bond network. Under the present experimental conditions, dehydration starts at 66 °C and within the 75 < T < 114 °C the presence of the T α anhydrous polymorphic form has been detected.

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Authors and Affiliations

  1. Dipartimento di Scienze della Terra, “Sapienza” Università di Roma, P. le A. Moro, 5, 00185, Rome, Italy

    Paolo Ballirano

  2. Dipartimento di Chimica, “Sapienza” Università di Roma, P. le A. Moro, 5, 00185, Rome, Italy

    Claudia Sadun

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  1. Paolo Ballirano
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  2. Claudia Sadun
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Correspondence to Paolo Ballirano.

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Ballirano, P., Sadun, C. Thermal behavior of trehalose dihydrate (T h) and β-anhydrous trehalose (T β) by in-situ laboratory parallel-beam X-ray powder diffraction. Struct Chem 20, 815–823 (2009). https://doi.org/10.1007/s11224-009-9473-5

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  • DOI: https://doi.org/10.1007/s11224-009-9473-5

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