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α-[Mn(O2CMe)2]: a two-dimensional coordination polymer of the anhydrous manganese acetate polymorphs

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Abstract

Two polymorphs of crystalline anhydrous manganese acetate, α-[Mn(O2CMe)2] (1) and β-[Mn(O2CMe)2] (2), were prepared under temperature-controlled solvothermal dehydration. X-ray single-crystal (and powder) diffractions revealed that compound 1 crystallizes in monoclinic (a = 9.763(4), b = 4.972(2), c = 6.122(3) Å, β = 102.878(5)°, V = 289.7(2) Å3, Z = 4) space group P2/c. Although it was early prepared, its single crystal structure is firstly determined and known as a two-dimensional (2D) layer structure; whereas, compound 2 demonstrates a three-dimensional diamondoid (dia-e) structure that people in its early X-ray single-crystal study was not aware of.

Graphical Abstract

Anhydrous α-[Mn(O2CMe)2] was discovered in 1967, which two-dimensional layer structure is firstly determined by the X-ray single-crystal analysis.

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Acknowledgment

We thank the National Science Foundation of P. R. China (NSFC) (No. 2003034003), The Foundation for the Author of National Excellent Doctoral Dissertation of P. R. China (FANEDD) (No. 200733) and the Education Foundation of Liaoning Province of P. R. China (EFLPC) (No. 20060470) for the finance Support.

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Authors and Affiliations

  1. Institute of Chemistry for Functionalized Materials, College of Chemistry and Chemical Engineering Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Jian Lin, Lei Yuan, Dong-Wei Guo, Gao Zhang, Shi-Yan Yao & Yun-Qi Tian

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  1. Jian Lin
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  2. Lei Yuan
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  3. Dong-Wei Guo
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  4. Gao Zhang
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Correspondence to Yun-Qi Tian.

Electronic supplementary material

XRD, IR, and TGA of compound 1 and 2, CIF file of compound 1 are offered.

Supplementary material 1 (DOC 1298 kb)

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Lin, J., Yuan, L., Guo, DW. et al. α-[Mn(O2CMe)2]: a two-dimensional coordination polymer of the anhydrous manganese acetate polymorphs. Struct Chem 20, 505–508 (2009). https://doi.org/10.1007/s11224-009-9447-7

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