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Benzamidinium acetylsalicylate: crystal structure of the first salt with acetylsalicylate anion

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Abstract

The first crystal structure of a non-coordinating acetylsalicylate anion containing salt was determined by X-ray crystallography. Benzamidinium acetylsalicylate crystallizes in the triclinic space group \( P\bar{1} \) (a = 9.8885(5), b = 10.2769(5), c = 15.2656(7) Å, α = 87.219(4), β = 78.261(4) and γ = 72.589(4) Z = 4, V = 1449.17(12) Å3, R1 = 0.0346 and wR2 = 0.0697). The structure comprises pairs of hydrogen bonded benzamidinium cations and acetylsalicylate anions connected into infinite chains through further N–H···O hydrogen bonds.

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Acknowledgments

B.K. wishes to thank the Alexander von Humboldt Foundation for the Fellowship and T.K. the DAAD for a grant within the priority program “Stability Pact South-Eastern Europe” and the Alexander von Humboldt Foundation

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Authors and Affiliations

  1. Institut für Umweltforschung, Universität Dortmund, Otto-Hahn-Strasse 6, 44221, Dortmund, Germany

    T. Kolev & M. Spiteller

  2. Lehrstuhl für Analytische Chemie, Ruhr-Universität Bochum, Universitätsstrasse 150, 44780, Bochum, Germany

    B. B. Koleva, R. W. Seidel & W. S. Sheldrick

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  1. T. Kolev
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  2. B. B. Koleva
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  3. R. W. Seidel
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  4. M. Spiteller
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  5. W. S. Sheldrick
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Correspondence to T. Kolev.

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Kolev, T., Koleva, B.B., Seidel, R.W. et al. Benzamidinium acetylsalicylate: crystal structure of the first salt with acetylsalicylate anion. Struct Chem 20, 533–536 (2009). https://doi.org/10.1007/s11224-009-9423-2

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  • DOI: https://doi.org/10.1007/s11224-009-9423-2

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