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Hydrothermal synthesis and crystal structure of Na(NH4)[C13N2H16]2[Mo7O24] · 8H2O: A novel 3-D extended supramolecular network with 1-D channels

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Abstract

A novel three-dimensional (3-D) supramolecular assembly of organic bicapped heptamolybdate Na(NH4)[C13N2H16]2[Mo7O24]·8H2O has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR spectra, elemental analysis, and thermogravimetric analysis (TGA). X-ray analyses show that compound 1 represent a novel 3-D extended supramolecular “host” networks with 1-D channels encapsulating flexible cation “guests”.

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Acknowledgments

The authors are thankful for the financial support from the National Natural Science Foundation of China (Grant Nos. 20371010; 20671017) and the Specialized Research Fund for the Doctoral Program of Higher Education.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Xiaoshu Qu, Lin Xu, Yanyan Yang, Fengyan Li, Weihua Guo, Liping Jia & Xizheng Liu

  2. JiLin Institute of Chemical Technology, JiLin City, 132073, People’s Republic of China

    Xiaoshu Qu

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  1. Xiaoshu Qu
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  2. Lin Xu
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  3. Yanyan Yang
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  4. Fengyan Li
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  5. Weihua Guo
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  6. Liping Jia
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  7. Xizheng Liu
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Correspondence to Lin Xu.

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Qu, X., Xu, L., Yang, Y. et al. Hydrothermal synthesis and crystal structure of Na(NH4)[C13N2H16]2[Mo7O24] · 8H2O: A novel 3-D extended supramolecular network with 1-D channels. Struct Chem 19, 801–805 (2008). https://doi.org/10.1007/s11224-008-9367-y

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  • DOI: https://doi.org/10.1007/s11224-008-9367-y

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