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Three novel octacyanomolybdate(IV)–M(II) [M = Mn and Cu] bimetallic assemblies: crystal structures and magnetic properties

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Abstract

Synthesis, structure characterization, and magnetic properties of three novel cyano-bridged complexes {[MnII(bpy)(DMF)2]2[MoIV(CN)8]·1.5H2O} n (1), [CuII(L)]2[MoIV(CN)8]·6.75H2O (2), and [MnII(bpy)2]4[MoIV(CN)8]2·4MeOH·4H2O (3) (where DMF = N,N′-dimethylformamide; bpy = 2,2-bipyridine and L = 1,3,6,8,11,14-hexaazatricyclo[12.2.1.18,11]octadecane) have been studied. The X-ray single-crystal structure reveals that 1 is a cyanide-bridged 1D infinite chain with the alternating of MnII(bpy)(DMF)2 and MoIV(CN)8 moieties. The neighboring chains interact with each other by hydrogen bonding to form a sheet-like network, and the layers further extend to a 3D network due to the face-to-face π···π stack interactions. For 2, the MoIV center adopts a distorted square antiprism coordination environment, while the CuII center adopts a distorted square pyramidal geometry. The weak Mo–CN···Cu interactions between neighboring molecules lead to a 2D network structure of 2. For 3, basic structural unit is centrosymmetric and contains four MnII centers bridged by two octacyanomolybdate(IV). Here, their magnetic properties have also been studied.

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References

  1. Sieklucka B, Podgajny R, Przychodzeń P, Korzeniak T (2005) Coord Chem Rev 249:2203

    Article  CAS  Google Scholar 

  2. Li DF, Yang DX, Li SA, Tang WX (2002) Inorg Chem Commun 5:791

    Article  CAS  Google Scholar 

  3. Podgajny R, Korzeniak T, Stadnicka K, Dromzée Y, Alcock NW, Errington W, Kruczała K, Bałanda M, Kemp TJ, Verdaguer M, Sieklucka B (2003) Dalton Trans 3458

  4. Sra AK, Andruh M, Kahn O, Golhen S, Ouahab L, Yakhmi JV (1999) Angew Chem Int Ed 38:2606

    Article  CAS  Google Scholar 

  5. Si SF, Liu X, Liao DZ, Yan SP, Jiang ZH, Cheng P (2003) J Coord Chem 56:337

    Article  CAS  Google Scholar 

  6. Herrera JM, Armentano D, de Munno G, Lloret F, Julve M, Verdaguer M (2003) New J Chem (Nouv J Chim) 27:128

    Article  CAS  Google Scholar 

  7. Chang F, Sun HL, Kou HZ, Gao S (2002) Inorg Chem Commun 5:660

    Article  CAS  Google Scholar 

  8. Rombaut G, Verelst M, Golhen S, Ouahab L, Mathoniere C, Kahn O (2001) Inorg Chem 40:1151

    Article  CAS  Google Scholar 

  9. Bonadio F, Gross M, Stoeckli-Evans H, Decurtins S (2002) Inorg Chem 41:5891

    Article  CAS  Google Scholar 

  10. You YS, Yoon JH, Lim JH, Kim HC, Hong CS (2005) Inorg Chem 44:7063

    Article  CAS  Google Scholar 

  11. Przychodzeń P, Lewiński K, Bałanda M, Pelka R, Rams M, Wasiutyński T, Guyard-Duhayon C, Sieklucka B (2004) Inorg Chem 43:2967

    Article  Google Scholar 

  12. You YS, Kim D, Do Y, Oh SJ, Hong CS (2004) Inorg Chem 43:6899

    Article  CAS  Google Scholar 

  13. Herrera JM, Marvaud V, Verdaguer M, Marrot J, Kalisz M, Mathonière C (2004) Angew Chem Int Ed 43:5468

    Article  CAS  Google Scholar 

  14. Song Y, Zhang P, Ren XM, Shen XF, Li YZ, You XZ (2005) J Am Chem Soc 127:3708

    Article  CAS  Google Scholar 

  15. (a) Larionova J, Gross M, Pilkington M, Andres H, Stoeckli-Evans H, Gudel HU, Decurtins S (2000) Angew Chem Int Ed Engl 39:1605; (b) Zhong ZJ, Seino H, Mizobe Y, Hidai M, Fujishima A, Ohkoshi S, Hashimoto K (2000) J Am Chem Soc 122:2952; (c) Lim JH, Yoon JH, Kim HC, Hong CS (2006) Angew Chem Int Ed Engl 45:7424; (d) Lim JH, Yoo HS, Yoon JH, Koh EK, Kim HC, Hong CS (2007) Polyhedron, doi: 10.1016/j.poly.2007.09.006

  16. Sieklucka B, Szklarzewicz J, Kemp TJ, Errington W (2000) Inorg Chem 39:5156

    Article  CAS  Google Scholar 

  17. Li DF, Gao S., Zheng LM, Tang WX (2002) J Chem Soc Dalton Trans 2805

  18. Withers JR, Li DF, Triplet J, Ruschman C, Parkin S, Wang GB, Yee GT, Holmes SM (2006) Inorg Chem 45:4307

    Article  CAS  Google Scholar 

  19. Willemin S, Larionova J, Clérac R, Donnadieu B, Henner B, Goff XFL, Guérin C (2003) Eur J Inorg Chem 1866

  20. Leipoldt JG, Bok LDC, Cilliers PJ (1974) Z Anorg Allg Chem 409:343

    Article  CAS  Google Scholar 

  21. Furman NH, Miller CO, Arvan PG, Audrieth LF (1950) Inorg Synth 3:160

    Article  Google Scholar 

  22. (a) Sheldrick GM (1997) SHELXS-97: Program for the solution of crystal structures. University of Göttingen, Germany. (b) Sheldrick GM (1997) SHELXL-97: Program for the refinement of crystal structures. University of Göttingen, Germany

  23. Zhao HH, Shatruk M, Prosvirin AV, Dunbar KR (2007) Chem Eur J 13:6573

    Article  CAS  Google Scholar 

  24. O’ Conner CJ (1992) Prog Inorg Chem 29:203

    Article  Google Scholar 

Download references

Acknowledgments

This project was supported by the National Natural Science Foundation of China 20631030 and National Basic Research Program of China 973 Program, 2007CB815305.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, P.R. China

    Shu-Lin Ma, Yue Ma, Shi Ren, Shi-Ping Yan & Dai-Zheng Liao

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  1. Shu-Lin Ma
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  2. Yue Ma
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  3. Shi Ren
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Correspondence to Dai-Zheng Liao.

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Ma, SL., Ma, Y., Ren, S. et al. Three novel octacyanomolybdate(IV)–M(II) [M = Mn and Cu] bimetallic assemblies: crystal structures and magnetic properties. Struct Chem 19, 329–338 (2008). https://doi.org/10.1007/s11224-008-9289-8

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