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The reaction between [RuCl2(PPh3)3] and hydroxyquinoline carboxylic acid

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Abstract

The reactions of [RuCl2(PPh3)3] with 8-hydroxy-2-methyl-quinoline-7-carboxylic acid was examined, and a novel ruthenium(II) complex—[Ru(PPh3)2(C5H8NO)2]—was obtained. The compound was studied by IR, UV–vis spectroscopy, and X-ray crystallography. The molecular orbital diagram of the complex was calculated with the density functional theory (DFT) method. The spin-allowed singlet–singlet electronic transitions of the compound were calculated using the time-dependent DFT method, and the UV–vis spectrum of the compound was discussed, on this basis. The luminescence property of the [Ru(PPh3)2(C5H8NO)2]was examined.

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Authors and Affiliations

  1. Department of Crystallography, Institute of Chemistry, University of Silesia, 9th Szkolna Street, 40-006, Katowice, Poland

    J. G. Małecki

  2. Institute of Physics, University of Silesia, 4th Uniwersytecka Street, 40-006, Katowice, Poland

    J. Kusz

  3. Department of X-Ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Lodz University of Technology, 116 Żeromski Street, 90-924, Lodz, Poland

    R. Kruszynski

  4. Department of Organic Chemistry, Institute of Chemistry, University of Silesia, 9th Szkolna St, 40-006, Katowice, Poland

    D. Tabak

  5. Polish Academy of Sciences, Centre of Polymer Chemistry, M. Sklodowskiej-Curie 34, Zabrze, 41-819, Poland

    Z. Mazurak

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  1. J. G. Małecki
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  2. J. Kusz
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Correspondence to J. G. Małecki.

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Małecki, J.G., Kusz, J., Kruszynski, R. et al. The reaction between [RuCl2(PPh3)3] and hydroxyquinoline carboxylic acid. Struct Chem 19, 257–263 (2008). https://doi.org/10.1007/s11224-007-9280-9

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  • DOI: https://doi.org/10.1007/s11224-007-9280-9

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