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Two new tetranuclear complexes of the macrocyclic oxamide [MCu3] (M = Cd, Mn, macrocyclic oxamide = 1,4,8,11-tetraazacyclotradecanne-2,3-dione): syntheses, spectra and magnetic properties

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Abstract

Two new tetranuclear complexes of macrocyclic oxamide [Cd(CuL)3](NO3)2·2.5H2O 1, [Mn(CuL)3(OH)2](ClO4)2·Mn(H2O)6·4.5H2O 2 (L = 1,4,8,11-tatraazacyclotradecanne-2,3-dione) have been synthesized, structurally characterized and preliminary investigated by magnetic studies. The structures of the title complexes consist of a tetranuclear units MCu3 (M = Cd, Mn), the packing diagram shows two-dimensional and three-dimensional system through intermolecular weak interactions. The temperature-dependent magnetic susceptibilities of complex 2 were analyzed by an approximate treatment leading to J = −33 cm−1, gCu = 2.10, gMn = 1.95 indicating antiferromagnetic exchange between Cu(II) and Mn(II) ions.

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Acknowledgments

The work is supported by the National Natural Science Foundation of China (No. 20471031, 20631030, 20331010).

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin , 300071, P. R. China

    Yan Ouyang, Yue Ma, Na Xu, Dai-Zheng Liao & Shi-Ping Yan

  2. Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto, 606-8502, Japan

    Wei Zhang & Kazuyoshi Yoshimura

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  1. Yan Ouyang
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  2. Wei Zhang
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  3. Yue Ma
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  4. Na Xu
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  5. Dai-Zheng Liao
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  7. Shi-Ping Yan
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Correspondence to Dai-Zheng Liao.

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Ouyang, Y., Zhang, W., Ma, Y. et al. Two new tetranuclear complexes of the macrocyclic oxamide [MCu3] (M = Cd, Mn, macrocyclic oxamide = 1,4,8,11-tetraazacyclotradecanne-2,3-dione): syntheses, spectra and magnetic properties. Struct Chem 18, 891–898 (2007). https://doi.org/10.1007/s11224-007-9211-9

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