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Synthesis and characterization of copper(II) chelate with a new substituted bis(2-pyridyl)-amine derivative

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Abstract

The novel ligand, abbreviated Ibdpam, has been synthesized and characterized as well as its novel mononuclear copper(II) complex. The crystal and molecular structure of the complex [CuII(Ibdpam)(SO4)(H2O)2]·H2O is reported. The square-based pyramidal arrangement of the chromophore CuN2O3, the bidentate chelate character for the nitrogenous base, and the unidentate character of the sulfate oxy-dianion is established.

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Acknowledgement

Authors would like to thank Professor George Voutsas from the Department of Physics of our university, for the facilities concerning the crystal data collection as well as the useful comments and discussions on the crystal structure solution.

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Authors and Affiliations

  1. Department of Chemistry, University of Thessaloniki, 54124, Thessalonica, Greece

    M. Kapnisti & A. G. Hatzidimitriou

  2. Laboratory of Inorganic Chemistry, Aristotle University of Thessaloniki, 54124, Thessaloniki, GR, Greece

    A. G. Hatzidimitriou

Authors
  1. M. Kapnisti
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  2. A. G. Hatzidimitriou
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Correspondence to A. G. Hatzidimitriou.

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Kapnisti, M., Hatzidimitriou, A.G. Synthesis and characterization of copper(II) chelate with a new substituted bis(2-pyridyl)-amine derivative. Struct Chem 18, 331–335 (2007). https://doi.org/10.1007/s11224-007-9147-0

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  • DOI: https://doi.org/10.1007/s11224-007-9147-0

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