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Solvothermal synthesis and structural characterization of a novel erbium(III)-carboxylate polymeric complex

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Abstract

A novel erbium(III)-carboxylate polymeric complex [{Er(H2btec)2/4(btec)3/6(H2O)}·2H2O] n , simplified as ECPC, (H4btec=1,2,4,5-benzenetetracarboxylic acid) was synthesized under solvothermal conditions (H2O/acetic acid). ECPC obtained was characterized by differential thermal analysis/thermogravimetry (DTA/TG), single-crystal X-ray diffraction, elemental analysis and FT-IR analysis techniques. The result of single-crystal X-ray diffraction analysis shows that the ECPC crystallizes in monoclinic symmetry, and the space group P2(1)/n, a=10.6933(15) Å, b=7.1243(10) Å, c=17.092(2) Å, α=γ=90°, β=97.109(2)°, V=1292.1(3) Å3, Z=4, R 1=0.0286, wR 2=0.0686. ECPC demonstrates a 3-D supramolecular framework containing nine-coordinate erbium centers and channels. The uncoordinated water molecules occupy the channels in ECPC. The results of TG/DTA, IR and elemental analysis performed also give positive information of the proposed crystal structure.

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Acknowledgement

This work was supported by the Doctoral Foundation of Jinan University.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Engineering, Jinan University, No.106, Jiwei Road, Jinan, 250022, Shandong, P.R. China

    Q. B. Bo, Z. X. Sun, Y. L. Sheng, Z. W. Zhang, G. X. Sun, C. L. Chen & Y. X. Li

  2. Department of Chemistry, Liaocheng University, Liaocheng, Shandong, 252059, P.R. China

    D. Q. Wang

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  1. Q. B. Bo
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  2. Z. X. Sun
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  3. Y. L. Sheng
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Correspondence to Q. B. Bo.

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Bo, Q.B., Sun, Z.X., Sheng, Y.L. et al. Solvothermal synthesis and structural characterization of a novel erbium(III)-carboxylate polymeric complex. Struct Chem 17, 609–615 (2006). https://doi.org/10.1007/s11224-006-9107-0

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  • DOI: https://doi.org/10.1007/s11224-006-9107-0

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