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Synthesis, structure and spectral characterisation of a hydrogen-bonded polymeric manganese(III) Schiff base complex

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Abstract

A new hydrogen-bonded polymeric Mn(III) complex C19H20Mn1N3O3S1 (1) has been synthesised by conventional procedure with a new Schiff base ligand (2Z,3Z)-N 1,N 2-bis(1-(2-hydroxyphenyl)ethylidene)ethane-1,2-diamine (H 2 L) bearing a tetradentate N2O2 donor site. The complex has been characterised with several spectroscopic techniques like FT-IR, UV/Vis and EPR and also well supported by variable temperature magnetic susceptibility study. The structure of the co-ordination complex has been unequivocally confirmed from single crystal X-ray diffraction study. The redox stability of the metal chelate complex has been investigated with a slow scan cyclic voltammetry.

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Acknowledgements

Financial assistance from the University Grants Commission and the Department of Science and Technology, Govt. of India, New Delhi is gratefully acknowledged. J. C. is also grateful to Ms. Maitri Mapa from the National Chemical Laboratory, Pune, for her kind academic help.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Kolkata, 700032, West Bengal, India

    Joy Chakraborty, Brajagopal Samanta & Samiran Mitra

  2. Groupe de Cristallographie et Ingénierie Moléculaire, Laboratoire des Multimatériaux et Interfaces, UMR 5615 CNRS, Université Claude Bernard-Lyon 1, Bât. Jules Raulin, 43 bd du 11 Novembre 1918, 69622, Villeurbanne Cedex, France

    Guillaume Pilet

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  1. Joy Chakraborty
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  2. Brajagopal Samanta
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Correspondence to Samiran Mitra.

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Chakraborty, J., Samanta, B., Pilet, G. et al. Synthesis, structure and spectral characterisation of a hydrogen-bonded polymeric manganese(III) Schiff base complex. Struct Chem 17, 585–593 (2006). https://doi.org/10.1007/s11224-006-9076-3

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