Skip to main content
SpringerLink
Log in

Study on one-dimensional chain coordination polymer [Cd(1,3,5-benzenetricarboxylate)(pyridine)3] n : diffusion synthesis, crystal structure, and thermal analyses

  • Original Paper
  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal of the coordination polymer [Cd(1,3,5-btc)(py)3] n (1; 1,3,5-btc: 1,3,5-benzenetricar- boxylate; py: pyridine) has been synthesized, cultured by diffusion method, and characterized by X-ray single crystal diffraction, elemental analysis, and FTIR spectroscopy. In 1,3,5-benzenetricarboxylates with two kinds of coordination styles as bridging ligands, the cadmium(III) centers are linked together to form one-dimensional molecular chains. Thermal decomposition mechanisms were predicted on the basis of TG–DTG curve and FTIR spectra of the chain coordination polymer. Kinetic equations of the second and third mass loss stages were determined from the DTG curve using integral and differential methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Yaghi OM, Li HL, Groy TL (1996) J Am Chem Soc 118:9096

    Article  CAS  Google Scholar 

  2. Chui SSY, Lo SMF, Charmant JPH, Orpen G, Williams ID (1999) Science 283:1148

    Article  CAS  Google Scholar 

  3. Yaghi OM, Davis CE, Li GM, Li HL (1997) J Am Chem Soc 119:2861

    Article  CAS  Google Scholar 

  4. Li HL, Eddaoudi M, O’Keeffe M, Yaghi OM (1999) Nature 402:276

    Article  CAS  Google Scholar 

  5. Eddaoudi M, Kim J, Wachter JB, Chae HK, O’Keeffe M, Yaghi OM (2001) J Am Chem Soc 123:4368

    Article  CAS  Google Scholar 

  6. Thirumurugan A, Natarajan S (2004) Eur J Inorg Chem 7:395

    CAS  Google Scholar 

  7. Song JL, Ma JG, Sun YQ, Clearfield A (2003) Eur J Inorg Chem 4218

  8. Wang ZQ, Kravtsov VC, Zaworotko MJ (2005) Angew Chem, Int Ed 44:2

    Google Scholar 

  9. (a) Long LS, Chen XM, Tong ML, Sun ZG, Ren YP, Huang RB, Zheng LS (2001) J Chem Soc, Dalton Trans 2888. (b) Deoghoria S, Sain S, Moulton B, Zaworotko MJ, Bera SK, Chandra SK (2002) Polyhedron 21:2457. (c) Zhang XF, Huang DG, Chen CN, Liu QT, Liao DZ, Li LC (2005) Inorg Chem Commun 8:22

  10. (a) Luo JH, Hong MC, Wang RH, Cao R, Han L, Lin ZZ (2003) Eur J Inorg Chem 2705. (b) Cui CP, Dai JC, Du WX, Fu ZY, Hu SM, Wu LM, Wu XT (2002) Polyhedron 21:175. (c) Ye Q, Chen XB, Song YM, Wang XS, Zhang J, Xiong RG, Fun HK, You XZ (2005) Inorg Chim Acta 358:1258. (d) Yan B, Song YS, Chen ZX (2004) J Mol Struct 694:115

  11. (a) Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM (2002) Science 295:469;. (b) Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM (2003) Science 300:1127. (c) Pan L, Liu HM, Lei XG, Huang XY, Olson DH, Turro NJ, Li J (2003) Angew Chem, Int Ed 42:542

  12. (a) Hohn F, Pantenburg I, Ruschewitz U (2002) Chem Eur J 8:4536. (b) Burrows AD, Donovan AS, Harrington RW, Mahon MF (2004) Eur J Inorg Chem 4686. (c) Niu WJ, Wong EH, Weisman GR, Peng YJ, Anderson CJ, Zakharov LN, Golen JA, Rheingold AL (2004) Eur J Inorg Chem 3310

  13. Sheldrick GM (1990) Acta Cryst A 46:467

    Article  Google Scholar 

  14. Sheldrick GM (1997) SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Germany

  15. Nyquist RA, Kagel RO (1971) Infrared spectra of inorganic compounds. Academic Press, New York, p. 225

    Google Scholar 

  16. (a) MacCallum JR, Tanner J (1968) Eur Polymer J 4:333. (b) Satava V, Sestak J (1971) Thermochim Acta 2:423. (c) Agrawal RKJ (1987) Therm Anal 32:149. (d) Achar BN, Brindley GW, Sharp JH (1966) In: Proceedings of the International Clay Conference, Jerusalem, vol. 1, p 67

  17. Bagchi TP, Sen PK (1981) Thermochim Acta 51:175

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The authors thank the National Natural Science Foundation of China (No. 20471008) and the Fundamental Research Foundation of Beijing Institute of Technology (BIT-UBF-200302B01 and BIT-UBF-200502B4221) for financial supports.

Author information

Authors and Affiliations

  1. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing, 100081, China

    Jinyu Guo, Tonglai Zhang, Jianguo Zhang, Yanhong Liu, Wei Yu & Ruifeng Wu

Authors
  1. Jinyu Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tonglai Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jianguo Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yanhong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Wei Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Ruifeng Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Tonglai Zhang.

Additional information

Supplementary materials

CCDC-604732 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.ac.uk/conts/retrieving. html [or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033; e-mail: deposit@ccdc.cam.ac.uk].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Guo, J., Zhang, T., Zhang, J. et al. Study on one-dimensional chain coordination polymer [Cd(1,3,5-benzenetricarboxylate)(pyridine)3] n : diffusion synthesis, crystal structure, and thermal analyses. Struct Chem 17, 577–583 (2006). https://doi.org/10.1007/s11224-006-9075-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-006-9075-4

Keywords

Search

Navigation